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GH690合金管材熱處理工藝優(yōu)化
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國家高技術(shù)研究發(fā)展計劃項目 (2008AA031703) ;新金屬材料國家重點實驗室自主課題 (2008-Z-12)


Optimization on Heat Treatment Processes of GH690 Tubes
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    摘要:

    以國外Inconel 690成品管的顯微組織為參照對象,對國產(chǎn)GH690合金管材在不同工藝條件下的固溶處理與TT處理工藝進行了研究;采用OM、SEM和TEM等表征手段分析了工藝參數(shù)對其晶粒度、晶界碳化物形貌和貧Cr區(qū)的影響。結(jié)果表明:國產(chǎn)GH690合金管在固溶處理過程中,隨著固溶溫度的提高,尺寸較大晶粒所占比例逐漸升高,長大激活能為265 kJ/mol。當固溶溫度超過1100 ℃時,保溫時間對晶粒尺寸影響顯著。國產(chǎn)GH690合金管析出細小半連續(xù)晶界碳化物的TT處理工藝參數(shù)為680 ℃/10~20 h,715 ℃/10~20 h,750 ℃/5~15 h。經(jīng)1090~1110 ℃/5 min固溶處理以及715 ℃/10 h或15 h的TT處理后,國產(chǎn)GH690合金管晶粒尺寸分布、晶界碳化物形貌特征和貧Cr區(qū)演化特征與國外Inconel 690成品管非常相似;而其TiN顆粒數(shù)量和尺寸明顯少于和小于后者,貧Cr區(qū)的最低Cr濃度高于后者。通過對顯微組織特征的綜合評價,表明國產(chǎn)GH690合金管的顯微組織總體優(yōu)于國外Inconel 690成品管。同時,兼顧實際生產(chǎn)中的成本問題,提出國產(chǎn)GH690合金管熱處理工藝優(yōu)化的建議。

    Abstract:

    The solution treatment and thermal treatment (TT) processes of GH690 tube made in China were investigated with different processing parameters including temperature and time. The microstructural features, consisting of the grain size, carbide morphology along grain boundary and chromium-depleted zone of the investigated GH690 tube, were characterized through OM, SEM and TEM and evaluated based on Inconel 690 commercial tube. The results indicate that the proportion of large grains in the investigated GH690 tube increases gradually with increasing the solution temperature. The activation energy of grain growth is 265 kJ/mol. The influence of time on grain size becomes significant once the solution treatment is above 1100 °C. Thermal treatment processes for promoting the formation of fine semi-continuous carbides along grain boundaries are 680 °C/10~20 h, 715 °C/10~20 h and 750 °C/5~15 h. Similar microstructural features, including grain size, carbide morphology along grain boundaries and chromium depletion profile, are observed in both the investigated GH690 tube and the Inconel 690 commercial tube after solution treatment at 1090~1110 °C for 5 min followed by thermal treatment at 715 °C for 10 h or 15 h. Nonetheless, the size and density of TiN are lower and the minimum chromium content is higher in the investigated GH690 tube than those in the Inconel 690 commercial tube. Overall, microstructural features in GH690 tube made in China are superior to those in Inconel 690 commercial tube. The optimized heat treatment process is suggested based on microstructure analyses as well as the consideration of economic cost in production.

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袁曉飛,王美玲,丁賢飛,鄭運榮,馮 強. GH690合金管材熱處理工藝優(yōu)化[J].稀有金屬材料與工程,2015,44(11):2887~2896.[Yuan Xiaofei, Wang Meiling, Ding Xianfei, Zheng Yunrong, Feng Qiang. Optimization on Heat Treatment Processes of GH690 Tubes[J]. Rare Metal Materials and Engineering,2015,44(11):2887~2896.]
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  • 收稿日期:2014-11-20
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  • 在線發(fā)布日期: 2016-07-29
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