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電鑄制備TiB2/Cu復(fù)合材料的性能
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國(guó)家自然科學(xué)基金(51105235);山東省自然科學(xué)基金(ZR2009FQ030)


Properties of Electroforming TiB2/Cu Composites
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    摘要:

    使用粒度約為3 μm的導(dǎo)電陶瓷TiB2顆粒作為銅基復(fù)合材料的增強(qiáng)相,在酸性硫酸銅溶液中用電鑄方法制備TiB2/Cu電火花加工用工具電極。用掃描電鏡和金相顯微鏡觀察其組織結(jié)構(gòu),用維氏硬度計(jì)測(cè)量硬度,用中性鹽霧試驗(yàn)測(cè)量其耐腐蝕性,用電火花加工脆硬材料衡量其抗電蝕性。結(jié)果表明:電鑄Cu與TiB2/Cu晶粒平均直徑分別為30,10 μm,硬度分別為984,1235 MPa,腐蝕失重分別為47.8,40.3 mg;TiB2顆粒的加入可顯著細(xì)化晶粒,提高硬度、耐腐蝕性和抗電蝕性。

    Abstract:

    Cu-based TiB2/Cu electrodes reinforced by conductive ceramic TiB2 particles with a particle size of about 3 mm were prepared by electroforming in acid H2SO4 solution. Their structure was observed by scanning electron microscopy and metallographic microscope, hardness was measured by Vickers hardness tester, the corrosion resistance was measured by salt spray tests, and the electric erosion resistance was evaluated by brittle-hard materials. The results show that the reinforcing TiB2 particles are uniformly distributed in the matrix. The particle size of the electroformed Cu and TiB2/Cu is 30 and 10 mm, the hardness is 984 and 1235 MPa, and the corrosion is 47.8 and 40.3 mg, respectively. Compared with Cu electricity deposit, TiB2/Cu composites have preferable surface, small grains and higher hardness, and this kind of composite material as an EDM tool electrode material show good corrosion resistance and electrical erosion resistance.

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戴春爽,李 麗.電鑄制備TiB2/Cu復(fù)合材料的性能[J].稀有金屬材料與工程,2015,44(11):2808~2811.[Dai Chunshuang, Li Li. Properties of Electroforming TiB2/Cu Composites[J]. Rare Metal Materials and Engineering,2015,44(11):2808~2811.]
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  • 收稿日期:2014-11-08
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  • 在線發(fā)布日期: 2016-07-29
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