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定向凝固速率對(duì)Al-Al2Cu過共晶合金中組織形態(tài)及取向變化的影響
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國家自然科學(xué)基金(50971101和51074127);凝固技術(shù)國家重點(diǎn)實(shí)驗(yàn)室資助項(xiàng)目(34-TP-2009)


Effect of Directional Solidification Rate on Microstructure and Orientation of Hypereutectic Al-Al2Cu Alloy
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    摘要:

    對(duì)Al-40%Cu(質(zhì)量分?jǐn)?shù))過共晶合金在2、10和100 μm/s速率下進(jìn)行定向凝固實(shí)驗(yàn),觀察了不同速率下的組織形態(tài),并分析造成組織形態(tài)差異是由于各相之間的競(jìng)爭(zhēng)生長(zhǎng)所致;采用X射線衍射技術(shù)對(duì)過共晶合金中Al2Cu相進(jìn)行宏觀極圖測(cè)試并計(jì)算其取向分布函數(shù)(ODF),同時(shí)采用EBSD技術(shù)對(duì)定向凝固樣品進(jìn)行微觀取向測(cè)試。結(jié)果表明:當(dāng)定向凝固速率為2 μm/s時(shí)合金組織為全共晶組織(Al/Al2Cu),其中的Al2Cu相取向集中在(001)方向;隨著凝固速率增加到10 μm/s時(shí),Al2Cu相優(yōu)先共晶相生長(zhǎng)形成初生Al2Cu相枝晶組織,具有小平面相生長(zhǎng)特征,其取向主要集中在(001)方向;當(dāng)凝固速率達(dá)到100 μm/s時(shí),Al2Cu相枝晶為非小平面特征的復(fù)雜枝晶形貌,其取向集中在(100),(110)和(001)等方向;且Al2Cu相枝晶沿著平行于定向凝固熱流方向生長(zhǎng)。XRD宏觀取向結(jié)果表明,取向更為集中的定向凝固組織在相對(duì)較低的抽拉速率下可以得到很好地控制。

    Abstract:

    The microstructure and orientation of directionally solidified Al-40%Cu hypereutectic alloy were investigated, and the different microstructures were formed because of the growth competition between eutectic phase and the primary Al2Cu phase. By X-ray diffraction techniques, the pole figures of Al2Cu phase were tested within the macro-orientations and the orientation distribution function (ODF) was calculated. Meanwhile the micro-orientations of directional solidification samples were determined by EBSD. At the directional solidification rate 2 μm/s, the microstructure is all eutectic (Al/Al2Cu) phase, in which Al2Cu phase has the orientation of (001) direction; however, at 10 μm/s the primary Al2Cu phase dendrite with faceted characteristic grows ahead of eutectic phase, which has mainly (001) orientation. When the solidification rate reaches 100 μm/s, Al2Cu phase with non-faceted characteristic grow into complex morphology, and its orientation focuses on the (100), (110) and (001) directions. Al2Cu phase grows along with the direction of?heat flux. The results of XRD analysis show that dendritic morphology and orientation can be well controlled under directional solidification with relatively lower rate.

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高 卡,李雙明,傅恒志.定向凝固速率對(duì)Al-Al2Cu過共晶合金中組織形態(tài)及取向變化的影響[J].稀有金屬材料與工程,2015,44(11):2762~2767.[Gao Ka, Li Shuangming, Fu Hengzhi. Effect of Directional Solidification Rate on Microstructure and Orientation of Hypereutectic Al-Al2Cu Alloy[J]. Rare Metal Materials and Engineering,2015,44(11):2762~2767.]
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  • 收稿日期:2014-11-15
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  • 在線發(fā)布日期: 2016-07-29
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