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Influence of Helium on Microstructure and Electrochemical Properties of LiFePO4 Thin Films Electrodes
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Influence of Helium on Microstructure and Electrochemical Properties of LiFePO4 Thin Films Electrodes
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National Natural Science Foundation of China (51171124); Scientific and Technical Supporting Programs funded by Sci & Tech Department of Sichuan Province (2014GZ0004); Program for New Century Excellent Talents in University (NCET-08-0380)

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    摘要:

    提出利用氦滲透法優(yōu)化LiFePO4材料的結(jié)晶生長過程,達到提高材料電化學(xué)性能的目的。采用磁控濺射法制備含氦LiFePO4薄膜電極,利用掃描電鏡觀察樣品的微觀形貌,發(fā)現(xiàn)樣品表面與截面皆呈現(xiàn)多孔結(jié)構(gòu)。用X射線衍射儀分析含氦LiFePO4薄膜電極的晶體結(jié)構(gòu)。結(jié)果表明,氦滲入薄膜后顯著增強了材料在29.81o的衍射峰強度,而此處正對應(yīng)了鋰離子在LiFePO4材料中的擴散路徑([010] 方向)。這表明含氦LiFePO4薄膜中存在有利于材料脫鋰/嵌鋰的結(jié)晶擇優(yōu)生長取向,會導(dǎo)致薄膜電極電化學(xué)性能的提高。

    Abstract:

    The changes of the crystal orientation and lattice defects have a considerable impact on the electrochemical performances of lithium ion electrodes. Here, a new method of controlling the crystal growth of the LiFePO4 films by helium permeation was developed. The helium-permeated LiFePO4 thin film cathodes were prepared by radio frequency (RF) magnetron sputtering deposition. The morphologies of the helium-permeated LiFePO4 samples characterized by scanning electron microscope (SEM) presented pore structure. The X-ray diffraction (XRD) results of the LiFePO4 thin film cathodes indicate that the permeation of helium results in a noticeable increase of peak intensity at the 29.81o, which is normal to the pathway for lithium ion conduction (the [010] direction). It is concluded that there exists a preferential crystal growth orientation of (010) face which is in favor for the reversible insertion/de-insertion of Li ions, and therefore leading to the improvement in electrochemical performance of LiFePO4 samples.

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王 茂,汪 淵. Influence of Helium on Microstructure and Electrochemical Properties of LiFePO4 Thin Films Electrodes[J].稀有金屬材料與工程,2015,44(11):2702~2706.[Wang Mao, Wang Yuan. Influence of Helium on Microstructure and Electrochemical Properties of LiFePO4 Thin Films Electrodes[J]. Rare Metal Materials and Engineering,2015,44(11):2702~2706.]
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  • 收稿日期:2015-04-15
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  • 在線發(fā)布日期: 2016-07-29
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