b,進一步通過Arrhenius方程分析得出不連續(xù)析出胞狀組織的激活能約為77.3-110.9 kJ/mol。界面激活能要遠低于Ni、Mn元素在Cu中擴散所需的激活能,表明沉淀相易于在晶界處形核析出。"/>

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Cu-20Ni-20Mn合金連續(xù)/不連續(xù)時效析出及其相互作用研究
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北京有色金屬研究總院,北京有色金屬研究總院,北京有色金屬研究總院,北京有色金屬研究總院,北京有色金屬研究總院,北京有色金屬研究總院

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TG146.1+1

基金項目:

國家自然科學基金項目(項目號51401026)


Research of Interaction between Continuous and Discontinuous Precipitation in Cu-20Ni-20Mn Alloy
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General Research Institute for Nonferrous Metals,General Research Institute for Nonferrous Metals,General Research Institute for Nonferrous Metals,General Research Institute for Nonferrous Metals,General Research Institute for Nonferrous Metals,

Fund Project:

the National Natural Science Foundation of China (51401026)

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    摘要:

    通過掃描電鏡、透射電鏡和小角散射研究了Cu-20Ni-20Mn合金在573 K ~ 698 K溫度下的時效析出行為,確定不連續(xù)析出和連續(xù)析出之間的相互作用。結(jié)果表明:當時效溫度低于623 K,沉淀相析出主要以不連續(xù)析出為主導。時效溫度大于673 K時,沉淀相析出則主要由連續(xù)析出和不連續(xù)析出共同控制。時效過程中,沉淀相優(yōu)先在晶界形核長大,形成由NiMn相和貧溶質(zhì)原子基體組成的片層狀不連續(xù)析出胞狀組織。然而連續(xù)析出沉淀相的存在會抑制不連續(xù)胞狀組織的長大,當沉淀相直徑約大于5 nm時,將能有效阻礙不連續(xù)析出胞狀組織界面前沿的遷移。利用Aaronson-Liu模型估算出不連續(xù)析出的晶界化學擴散混合積sδDb,進一步通過Arrhenius方程分析得出不連續(xù)析出胞狀組織的激活能約為77.3-110.9 kJ/mol。界面激活能要遠低于Ni、Mn元素在Cu中擴散所需的激活能,表明沉淀相易于在晶界處形核析出。

    Abstract:

    The discontinuous and continuous precipitation behavior, and the interaction between them during the aging process in a Cu-20Ni-20Mn alloy have been investigated in the temperature range 573 K-698 K by scanning electron microscope (SEM), transmission electron microscopy (TEM) and small-angle X-ray scattering (SAXS). The results show that discontinuous precipitation is the predominant mechanism at 623 K and below, whereas both discontinuous and continuous precipitations occur when the temperature is higher than 673 K. The discontinuous precipitations with a lamellar mixed structure, consisting of alternate lamellae of matrix and NiMn phase, nucleate and grow preferentially on grain boundaries during the aging process. Continuous precipitations can either partially or completely inhibit the growth of discontinuous precipitation colonies. Obvious inhibition action on the migration of reaction front of discontinuous precipitation colonies are found by experimental results, owing to the continuous precipitates when their diameters reach up to about 5 nm or larger. The grain boundary chemical diffusion triple product sδDb is calculated according to an Aaronson-Liu model. In addition, the activation energy for discontinuous precipitation is determined to be in range between 106.7 to 113.5 kJ/mol based on Arrhenius equation, well below the activation energy for volume-bulk diffusion of Ni and Mn in Cu-rich alloy, indicating that discontinuous precipitation is easy to occur in grain boundaries.

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謝偉濱,王強松,解國良,劉冬梅,米緒軍,高學成. Cu-20Ni-20Mn合金連續(xù)/不連續(xù)時效析出及其相互作用研究[J].稀有金屬材料與工程,2017,46(12):3799~3804.[Xie Weibin, Wang Qiangsong, Xie Guoliang, Liu Dongmei, Mi Xujun, Gao Xuecheng. Research of Interaction between Continuous and Discontinuous Precipitation in Cu-20Ni-20Mn Alloy[J]. Rare Metal Materials and Engineering,2017,46(12):3799~3804.]
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  • 收稿日期:2015-10-27
  • 最后修改日期:2015-12-22
  • 錄用日期:2016-01-14
  • 在線發(fā)布日期: 2018-01-04
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