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工藝參數(shù)對(duì)Zn-4.5Cu-0.2Mn-0.3Bi合金水平連鑄坯反偏析及凝固組織的影響
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國(guó)家自然科學(xué)基金 (51071035, 51375070);高等學(xué)校博士學(xué)科點(diǎn)專(zhuān)項(xiàng)科研基金 (20100041110030)


Effect of Technical Parameters on the Inverse Segregation and Solidification Structure of Horizontal Continuous Casting Billet of Zn-4.5Cu-0.2Mn-0.3Bi Alloy
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    摘要:

    研究了鋅銅合金在電磁場(chǎng)下水平連鑄坯的初生坯殼前沿位置變化規(guī)律,考察了鑄坯橫截面宏觀組織、微觀組織形貌及合金元素的分布。試驗(yàn)結(jié)果表明,坯殼前沿的位置是隨著拉坯速度、澆注溫度和電流強(qiáng)度的變化而變化的,其中尤以拉坯速度對(duì)其的影響最為明顯。只有根據(jù)電流強(qiáng)度和澆注溫度相對(duì)應(yīng)調(diào)整拉坯速度才能達(dá)到改善組織和偏析的效果。較大的電流和拉坯速度促使坯殼前沿后移。當(dāng)液-固界面位于冷卻水套和攪拌器的交界處時(shí),反偏析得到有效抑制。電磁場(chǎng)消除了普通水平連鑄坯橫截面組織不均勻、最后凝固點(diǎn)上移的現(xiàn)象。攪拌后上邊緣和心部深灰色樹(shù)枝狀的富銅相并沒(méi)有完全消失,只是尺寸略微變大,但邊部和心部組織差異很小。當(dāng)拉坯速度3 m/h、電流100 A時(shí),邊部和心部組織最為均勻細(xì)小,其他電流和頻率時(shí)組織變化不大。Ti沒(méi)有起到細(xì)化作用和抑制反偏析作用,反而使得液體變得粘稠,流動(dòng)性變差

    Abstract:

    The paper studied the change rule of the forepart of initial solidified shell, cross-section structure and elements distribution of horizontal continuous casting Zn-Cu alloy billets under electromagnetic field. The results show that the forepart position changes with the casting speed, pouring temperature and current intensity. Among these parameters, casting speed plays the most important role. It is only adjusting the corresponding casting speed according to the current strength and the pouring temperature that can improve the structure and reduce segregation. The forepart moves backwards by enhancing the current and the casting speeds. When the liquid-solid interface locates in the interspace between the cooling water jacket and the electromagnetic stirrer, the inverse segregation of Cu can be effectively suppressed. Electromagnetic field removes the nonuniform cross-section structures and the difference between the final solidification area and billet geometric center, and refines the dendrite structure. Stirring does not completely eliminate the deep gray dendritic copper rich phases in the edge or center of the billets, instead of slightly larger dendrite sizes and the small edge-center structure difference. When casting speed and current intensity is 3 m/h and 100 A, respectively, the most uniform and refined structure is obtained, while no obvious change can be seen for other currents and frequencies. The addition of Ti cannot refine the billet structure or eliminate the inverse segregation, but make the melt sticky with poor fluidity

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曹志強(qiáng),陳 飛,李孝建,郭 俊,王繼軍,李廷舉.工藝參數(shù)對(duì)Zn-4.5Cu-0.2Mn-0.3Bi合金水平連鑄坯反偏析及凝固組織的影響[J].稀有金屬材料與工程,2015,44(10):2571~2575.[Cao Zhiqiang, Chen Fei, Li Xiaojian, Guo Jun, Wang Jijun, Li Tingju. Effect of Technical Parameters on the Inverse Segregation and Solidification Structure of Horizontal Continuous Casting Billet of Zn-4.5Cu-0.2Mn-0.3Bi Alloy[J]. Rare Metal Materials and Engineering,2015,44(10):2571~2575.]
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  • 收稿日期:2014-10-17
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  • 在線發(fā)布日期: 2016-07-13
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