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Ti-6Al-4V在溴化鋰溶液中的初期空化腐蝕研究
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南昌航空大學(xué) 輕合金加工科學(xué)與技術(shù)國(guó)防重點(diǎn)學(xué)科實(shí)驗(yàn)室,南昌航空大學(xué) 輕合金加工科學(xué)與技術(shù)國(guó)防重點(diǎn)學(xué)科實(shí)驗(yàn)室,南昌航空大學(xué) 輕合金加工科學(xué)與技術(shù)國(guó)防重點(diǎn)學(xué)科實(shí)驗(yàn)室,南昌航空大學(xué) 輕合金加工科學(xué)與技術(shù)國(guó)防重點(diǎn)學(xué)科實(shí)驗(yàn)室

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TG172.9

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國(guó)家自然科學(xué)基金(51361024)和江西省研究生創(chuàng)新專項(xiàng)資金項(xiàng)目(YC2014-S380)


Research on the initial cavitation corrosion of Ti-6Al-4V alloy in LiBr solution
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National Defence Key Discipline Laboratory of Light Alloy Processing Science and Technology Institute,Nanchang Hangkong University,National Defence Key Discipline Laboratory of Light Alloy Processing Science and Technology Institute,Nanchang Hangkong University,National Defence Key Discipline Laboratory of Light Alloy Processing Science and Technology Institute,Nanchang Hangkong University,National Defence Key Discipline Laboratory of Light Alloy Processing Science and Technology Institute,Nanchang Hangkong University

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    摘要:

    利用掃描電鏡、粗糙度輪廓儀、三維視頻顯微鏡和電化學(xué)測(cè)試技術(shù)研究了Ti-6Al-4V合金在溴化鋰溶液中空化腐蝕的破壞過(guò)程及腐蝕和空化的協(xié)同作用。從粗糙度、平均空化腐蝕深度和微觀形貌隨時(shí)間的變化觀察到Ti-6Al-4V合金空化腐蝕破壞的三個(gè)階段:線性增長(zhǎng)的初始階段;增長(zhǎng)速率降低的過(guò)渡階段;粗糙度基本不變的穩(wěn)定階段。Ti-6Al-4V合金的低強(qiáng)度α相吸收空泡潰滅產(chǎn)生的沖擊能優(yōu)先發(fā)生塑性變形,材料表面變形不均勻,在空化作用下α相局部區(qū)域表面鈍化膜破裂并暴露出鈦合金基體,由于α相電位低于β相,形成小陽(yáng)極大陰極,同時(shí)腐蝕物和腐蝕產(chǎn)物在空化的攪拌作用下能夠及時(shí)擴(kuò)散,加速了腐蝕溶解,產(chǎn)生的腐蝕坑又導(dǎo)致局部?jī)?nèi)應(yīng)力更加集中而加強(qiáng)力學(xué)因素,表面凹凸程度增加??栈W(xué)和電化學(xué)腐蝕的共同作用使腐蝕坑繼續(xù)發(fā)展并促進(jìn)了新腐蝕坑的生成,腐蝕坑周邊的β相發(fā)生脫落,從而導(dǎo)致表面凹凸程度降低。初期階段,電化學(xué)腐蝕促進(jìn)了空化作用。

    Abstract:

    In this paper, the evolution of cavitation corrosion of Ti-6Al-4V alloy in LiBr solution was discussed by means of SEM, roughness profiler, three-dimensional video microscope and electrochemical measurement. The results of the variation of surface roughness value (Rq), mean cavitation corrosion depth and morphological features indicate that there are three stages of cavitation corrosion process of Ti-6Al-4V alloy. At initial stage, the value of Rq increases linearly with time; at transition stage, the growth rate of Rq decreases; when the steady-state stage reaches, the value of Rq tends to stabilize. Plastic deformation of the low intensive α phase of Ti-6Al-4V alloy occurs preferentially due to absorption of impact energy generated by bubble collapse, causing uneven deformation of material surface. Passive film on the surface of α phase in local area is easily attacked and fresh titanium alloy substrate is exposed. Small anode and large cathode form due to relatively low electric potential of α phase in comparison with β phase, meanwhile corrosives and corrosion products diffuse fast with the aid of agitation of cavitation, leading to the acceleration of the corrosion dissolution. The growth of pits causes the concentration of local internal stress, which strengthens the mechanical factor, accordingly increases the degree of surface concave and convex. The synergetic effect of mechanics and electrochemical corrosion results in the development of the existing pits and emergence of new pits. Eventually β phase distributed at the boundary of pits falls off and the degree of surface concave and convex becomes small. At the initial stage, electrochemical corrosion promotes mechanical effect of cavitation.

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趙曉斌,林翠,楊穎,張翼飛. Ti-6Al-4V在溴化鋰溶液中的初期空化腐蝕研究[J].稀有金屬材料與工程,2017,46(12):3935~3940.[ZHAO Xiaobin, LIN Cui, YANG Ying, ZHANG Yifei. Research on the initial cavitation corrosion of Ti-6Al-4V alloy in LiBr solution[J]. Rare Metal Materials and Engineering,2017,46(12):3935~3940.]
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  • 收稿日期:2015-09-25
  • 最后修改日期:2015-11-10
  • 錄用日期:2015-12-08
  • 在線發(fā)布日期: 2018-01-04
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