18Cr2Mg3)相,合金的淬火敏感性最高。實驗研究表明與冷卻速率960℃/s處相比,冷卻速率1.8℃/s處7075、7055、7050和7085四種合金淬火態(tài)的電導(dǎo)率差值和時效態(tài)的硬度下降率均減小,硬度下降率分別為35.5%、19%、13.8%和9.5%,此處四個合金固溶體的晶格常數(shù)及淬火析出相的尺寸及面積分?jǐn)?shù)依次減小,因此其淬火敏感性依次降低。"/>

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四種Al-Zn-Mg-Cu合金淬火敏感性研究
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中南大學(xué) 輕合金研究院,中南大學(xué) 輕合金研究院,中南大學(xué)材料科學(xué)與工程學(xué)院,中南大學(xué)材料科學(xué)與工程學(xué)院,中南大學(xué)材料科學(xué)與工程學(xué)院

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國家重點基礎(chǔ)研究發(fā)展計劃資助項目(項目號2012CB619500)


Quench sensitivity of four Al-Zn-Mg-Cu aluminum alloys
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Light Alloy Research Institute,Central South University,Light Alloy Research Institute,Central South University,,,

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    摘要:

    采用第一性原理在JMatPro7.0軟件的Al基數(shù)據(jù)庫完成四種Al-Zn-Mg-Cu合金時間-溫度-轉(zhuǎn)變(TTT)曲線和CCT曲線計算。結(jié)論是: 7055合金的主合金元素總量及Cu含量最高,TTT曲線和CCT曲線在左上方;7085合金的Cu含量最低且Zn/Mg比值最高,TTT曲線和CCT曲線在右下方,平衡相析出的孕育期最長,開始析出溫度和鼻尖溫度最低,合金的淬火敏感性最低;7075合金Zn/Mg比值最小且晶內(nèi)存在非共格的E(Al18Cr2Mg3)相,合金的淬火敏感性最高。實驗研究表明與冷卻速率960℃/s處相比,冷卻速率1.8℃/s處7075、7055、7050和7085四種合金淬火態(tài)的電導(dǎo)率差值和時效態(tài)的硬度下降率均減小,硬度下降率分別為35.5%、19%、13.8%和9.5%,此處四個合金固溶體的晶格常數(shù)及淬火析出相的尺寸及面積分?jǐn)?shù)依次減小,因此其淬火敏感性依次降低。

    Abstract:

    The time-temperature-transformation(TTT) curves and CCT curves of four Al-Zn-Mg-Cu alloys were completed in the Al-based database of software JMatPro7.0 with the first principles. To conclude, for 7055 alloy with the highest gross amount of main alloying elements and highest Cu element content, TTT and CCT curves were at the top left. For 7085 alloy with the lowest Cu element content and highest Zn/Mg ratio, TTT and CCT curves were at the bottom right, thus the incubation of equilibrium phase precipitation was the longest, start precipitation temperature and the nose temperature were the lowest, and therefore the quench sensitivity was the lowest. For 7075 alloy with the lowest Zn/Mg ratio and the incoherent E (Al18Cr2Mg3) phase within grains, the quench sensitivity was the highest. The results show that compared with the conductivity of as-quenched and hardness as-aged at 960℃/s, the conductivity difference and hardness drop rates for 7075,7055,7050,7085 four alloys cooled at 1.8℃/s were decreased and the hardness drop rates were 35.5%, 19%, 13.8% and 9.5% respectively. The lattice constant and the size and area fraction of the quench-induced phases for the four alloys cooled at 1.8℃/s reduced, and thus the quench sensitivity decreased.

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李承波,張新明,王邵玲,劉勝膽,鄧運來.四種Al-Zn-Mg-Cu合金淬火敏感性研究[J].稀有金屬材料與工程,2017,46(11):3374~3381.[LI Chengbo, ZHANG Xinming, Wang Shaoling, LIU Shengdan, DENG Yunlai. Quench sensitivity of four Al-Zn-Mg-Cu aluminum alloys[J]. Rare Metal Materials and Engineering,2017,46(11):3374~3381.]
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  • 收稿日期:2015-09-14
  • 最后修改日期:2015-10-27
  • 錄用日期:2015-11-18
  • 在線發(fā)布日期: 2017-12-13
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