3Fe和Al-Fe-Er等富Fe相,第二級(jí)較低溫的均勻化熱處理有利于富Fe共晶相的球化和尺寸細(xì)化。研究結(jié)果還顯示,均勻化制度顯著影響析出相的析出行為。560℃/30h單級(jí)均勻化后的緩冷過(guò)程中有大量桿狀β’(Al3Mg2)和球狀A(yù)l3(Er, Zr)、Al3Zr相析出,但分布、尺寸很不均勻,析出相的總體積分?jǐn)?shù)最高,為7.4%;第二級(jí)均勻化有利于細(xì)小均勻的Al3(Er, Zr)、Al3Zr納米析出相形成,其中第二級(jí)均勻化溫度為150℃時(shí)更有利于其彌散形核,析出相數(shù)量密度最高(20.3um-1)、尺寸最細(xì)小(平均半徑14nm);采用三級(jí)均勻化處理可以在控制粒子尺寸的前提下,獲得較高的數(shù)量密度。"/>

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均勻化退火對(duì)5052含Er鋁合金顯微組織的影響
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重慶大學(xué) 材料科學(xué)與工程學(xué)院,重慶大學(xué) 材料科學(xué)與工程學(xué)院,重慶大學(xué) 材料科學(xué)與工程學(xué)院,重慶大學(xué) 材料科學(xué)與工程學(xué)院

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國(guó)家國(guó)際科技合作專(zhuān)項(xiàng)項(xiàng)目(2011DFR50950);重慶大學(xué)大型儀器設(shè)備開(kāi)放基金


Effects of homogenization treatment on the microstructures of 5052-Er Al alloy
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College of Materials Science and Engineering,Chongqing University,Chongqing,400044,College of Materials Science and Engineering,Chongqing University,Chongqing,400044,College of Materials Science and Engineering,Chongqing University,Chongqing,400044,College of Materials Science and Engineering,Chongqing University,Chongqing,400044

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    利用光學(xué)顯微鏡、掃描電子顯微鏡、透射電子顯微鏡等手段研究了單級(jí)、雙級(jí)和三級(jí)均勻化熱處理對(duì)新型5052含Er鋁合金顯微組織的影響。研究結(jié)果表明,合金經(jīng)560℃/30h高溫均勻化熱處理后,鑄態(tài)組織中存在的非平衡共晶相大部分發(fā)生回溶,未溶的共晶相是Al3Fe和Al-Fe-Er等富Fe相,第二級(jí)較低溫的均勻化熱處理有利于富Fe共晶相的球化和尺寸細(xì)化。研究結(jié)果還顯示,均勻化制度顯著影響析出相的析出行為。560℃/30h單級(jí)均勻化后的緩冷過(guò)程中有大量桿狀β’(Al3Mg2)和球狀A(yù)l3(Er, Zr)、Al3Zr相析出,但分布、尺寸很不均勻,析出相的總體積分?jǐn)?shù)最高,為7.4%;第二級(jí)均勻化有利于細(xì)小均勻的Al3(Er, Zr)、Al3Zr納米析出相形成,其中第二級(jí)均勻化溫度為150℃時(shí)更有利于其彌散形核,析出相數(shù)量密度最高(20.3um-1)、尺寸最細(xì)小(平均半徑14nm);采用三級(jí)均勻化處理可以在控制粒子尺寸的前提下,獲得較高的數(shù)量密度。

    Abstract:

    The effects of single-step, two-step and three-step homogenization treatments on the microstructures of 5052-Er Al alloy were studied by optical microscopy, scanning electron microscopy and transmission electron microscopy. The results showed that after 560℃/30h high temperature homogenization treatment, most of the non-equilibrium eutectic phases existed in the as-cast alloy dissolved, with the remaining phases being Fe-rich phases like Al3Fe and Al-Fe-Er. The second step treatment performing at lower temperature was found to be beneficial to the spherization and refinement of the Fe-rich phases. The results also showed that homogenization treatment regimes had an obvious effect on the precipitation behavior of the fine precipitates. During the slow cooling process from 560℃/30h isothermally holding to room temperature, there were a large amount of rod β’(Al3Mg2) and spherical Al3(Er, Zr) and Al3Zr phases precipitating out of the matrix. The total volume fraction of the precipitates, 7.4%, was the highest among the four regimes conducted in this experiment. However, these precipitates distributed unevenly and their sizes differed greatly with each other. The second step treatment favored the formation of fine and homogenously distributed precipitates of Al3(Er, Zr) and Al3Zr. When the second step treatment was carried out at 150℃, the quantity density of the precipitates was the highest (20.3um-1) with the finest particle size(average radius being 14nm). Three-step homogenization treatment could obtain a higher quantity density while maintaining a comparable particle size with that in two-step treatment.

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張靜,唐聰,趙婧婧,左汝林.均勻化退火對(duì)5052含Er鋁合金顯微組織的影響[J].稀有金屬材料與工程,2017,46(11):3491~3497.[Zhang Jing, Tang Cong, Zhao Jingjing, Zuo Rulin. Effects of homogenization treatment on the microstructures of 5052-Er Al alloy[J]. Rare Metal Materials and Engineering,2017,46(11):3491~3497.]
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  • 收稿日期:2015-08-18
  • 最后修改日期:2015-11-11
  • 錄用日期:2015-12-08
  • 在線發(fā)布日期: 2017-12-13
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