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微通道內(nèi)TiN、TiO2涂層的制備及抑焦效果研究
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國家自然科學(xué)基金(20903067);四川大學(xué)優(yōu)秀青年學(xué)者科研基金(2013SCU04A05);留學(xué)回國人員科研啟動基金(20111139-10-10)


Preparation and Anti-coking Effect of TiN, TiO2 Coatings in Microchannels
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    摘要:

    為了緩解換熱通道壁面金屬催化結(jié)焦,在溫度為800 ℃,時(shí)間為2 h條件下,實(shí)現(xiàn)了內(nèi)徑為2 mm,長度700 mm的304不銹鋼管道內(nèi)表面TiN涂層的化學(xué)氣相沉積(CVD);進(jìn)一步,在700 ℃的氧化氣氛中,將TiN涂層氧化得到TiO2涂層。采用掃描電子顯微鏡(SEM)、能量散射X射線譜(EDS)和X射線衍射(XRD)儀等分別檢測了涂層的形貌、元素組成和晶型結(jié)構(gòu)。檢測結(jié)果表明,CVD法制備的TiN、TiO2涂層表面均勻完整,粒子結(jié)合緊密,其組成基本符合化學(xué)計(jì)量比;其中TiN為立方晶相結(jié)構(gòu),TiO2為金紅石相結(jié)構(gòu)。以某種碳?xì)淙剂螦為原料采用自制的超臨界裂解裝置對TiN、TiO2涂層的抑制結(jié)焦效果進(jìn)行了初步評價(jià)。結(jié)果表明,與304空白管相比,TiN涂層管和TiO2涂層管高溫穩(wěn)定運(yùn)行時(shí)間明顯延長,其中TiN涂層管抑焦效果更加顯著。

    Abstract:

    In order to inhibit the metal catalytic coking, a TiN coating was deposited on the inner surface of stainless steel oil duct with the internal diameter of 2 mm and the length of 700 mm by chemical vapor deposition (CVD), in the process of which the deposition temperature was set as 800 °C for 2 h. Furthermore, the TiN coating turned into TiO2 coating in oxidizing atmosphere at 700 °C. The coating’s morphological features and textures were characterized by SEM, EDS and XRD. As shown in SEM, the surface of the TiN and TiO2 coating prepared by CVD, is continuous, close-packed and homogeneous. According to the observation of EDS, both of them are stoichiometric. The results from XRD indicate that the TiN in the coating has cub phase and the TiO2 has rutile phase. A supercritical cracking system was set up for preliminary evaluating of the coking inhibition characteristic of two kinds of inhibitors and with some hydrocarbon fuel A as feedstock. The results show that compared with the 304 blank tube, the duration time of fuel cracking at high temperature is enhanced obviously in TiN and TiO2 coating tubes, and the anti-coking performance of TiN is more significant.

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王 佳,唐石云,朱 權(quán),王健禮,李象遠(yuǎn).微通道內(nèi)TiN、TiO2涂層的制備及抑焦效果研究[J].稀有金屬材料與工程,2015,44(7):1740~1745.[Wang Jia, Tang Shiyun, Zhu Quan, Wang Jianli, Li Xiangyuan. Preparation and Anti-coking Effect of TiN, TiO2 Coatings in Microchannels[J]. Rare Metal Materials and Engineering,2015,44(7):1740~1745.]
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  • 收稿日期:2014-07-20
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  • 在線發(fā)布日期: 2016-01-04
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