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退火處理對Al/ZE42/Al復合板界面組織和腐蝕行為的影響
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遼寧科技大學,遼寧科技大學

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國家自然科學基金資助(項目號51404137);遼寧省重點實驗室開放基金(項目號2008329)


Influence of Annealing Treatment on Interfacial Microstructure and Corrosion Behavior of Al/ZE42/Al Composite Plate
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University of Science and Technology Liaoning,University of Science and Technology Liaoning

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    摘要:

    采用光學顯微鏡、掃描電鏡觀察顯微組織、鹽水浸泡測定腐蝕速率等方法,研究了退火熱處理工藝對Al/ZE42/Al復合板界面微觀組織以及復合板在5.0wt%NaCl水溶液中腐蝕行為的影響。結果表明:Al/ZE42/Al復合板經(jīng)退火處理后,界面區(qū)域發(fā)生Mg和Al等元素的互擴散,界面擴散層包含2個反應層,靠近ZE42鎂合金一側的反應層為Mg17Al12,靠近Al板一側的反應層為Al3Mg2金屬間化合物,隨退火溫度的升高或者保溫時間的延長,使ZE42/Al界面擴散層厚度增加,ZE42鎂合金發(fā)生了再結晶組織轉變;退火熱處理沒有改善Al/ZE42/Al復合板耐腐蝕性,提高了腐蝕速率,腐蝕機制為復合板邊部向內(nèi)部擴散而導致的電偶腐蝕加劇。

    Abstract:

    The microstructures and morphologies of Al/ZE42/Al composite plates were observed by optical microscopy (OM), scanning electron microscopy (SEM). Corrosion rates of the Al/ZE42/Al composite plates at different temperature and holding time were also measured in salt water immersion test, and the influence of annealing on interfacial microstructure of Al/ZE42/Al composite plates and corrosion behaviors in 5.0 wt% NaCl aqueous solution were investigated. The results showed that element diffusion of Mg, Al, Zn, Y and Er in Al/ZE42/Al composite plate interfacial region after annealing was occurred. The interfacial diffusion layer has two reaction layers. Mg17Al12 phase in one reaction layer near ZE42 magnesium alloy, and Al3Mg2 phase in the other reaction layer closed to Al plate. With annealing temperature and holding time increasing, the thickness of ZE42/Al interfacial diffusion layer increased, and at the meanwhile recrystallization behaviors occurred in ZE42 magnesium alloy. Annealing cannot improve corrosion resistance of Al/ZE42/Al composite plate, but improving corrosion rate. The corrosion mechanism of the Al/ZE42/Al composite plate is the aggravation of galvanic corrosion which occurred from edge to internal of the plate.

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劉悅,王忠軍.退火處理對Al/ZE42/Al復合板界面組織和腐蝕行為的影響[J].稀有金屬材料與工程,2016,45(6):1571~1577.[liu yue, wang zhong jun. Influence of Annealing Treatment on Interfacial Microstructure and Corrosion Behavior of Al/ZE42/Al Composite Plate[J]. Rare Metal Materials and Engineering,2016,45(6):1571~1577.]
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  • 收稿日期:2015-07-13
  • 最后修改日期:2015-09-29
  • 錄用日期:2015-10-13
  • 在線發(fā)布日期: 2016-10-08
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