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Combustion Synthesis of Fe-Cu-TiC Composites under Electric Field
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Combustion Synthesis of Fe-Cu-TiC Composites under Electric Field
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Scientific Research Foundation for the Returned Overseas Chinese Scholars (20101561-3-1)

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    摘要:

    以配料比為15%(Ti+C)-65%Fe-20%Cu (質(zhì)量分?jǐn)?shù))(Ti:C化學(xué)計(jì)量比為1:1)的Fe-Cu-Ti-C體系為研究對象,研究該體系在不同溫度下的燃燒合成過程。Fe-Cu-TiC復(fù)合材料在759 ℃的點(diǎn)火溫度下完成電場輔助燃燒合成,該電場輔助由Gleeble-3500D熱模擬機(jī)提供。Fe-Cu-Ti-C體系燃燒合成的四步模型被提出,描述了Fe-Cu-TiC復(fù)合材料的在電場作用下的燃燒合成過程。它包括 (I) 預(yù)熱階段、(II)固相擴(kuò)散階段、(III) 燃燒合成階段、(IV) 后續(xù)階段。從階段I到階段II,反應(yīng)物原子的固相擴(kuò)散隨著溫度的增加而增加。從階段II到階段III,C原子擴(kuò)散到Ti原子,直至緊密的與其接觸。在III的初始階段,Ti開始和C在界面處發(fā)生反應(yīng):Ti(s) + C(s) =TiC(s),并且Ti粒子周圍形成一層很薄的固相產(chǎn)物TiC層。在III的后續(xù)階段,C原子穿過固相產(chǎn)物TiC層,擴(kuò)散到Ti粒子中,繼續(xù)發(fā)生化學(xué)反應(yīng),直到TiC粒子析出。在第IV階段,TiC顆粒逐漸的形核和長大,在SEM中可以看出TiC是球形顆粒。

    Abstract:

    Fe-Cu-TiC composites were synthesized and consolidated simultaneously at an ignition temperature of 759 °C by electric field-assisted combustion synthesis (EFACS). This electric field was generated by a Gleeble thermal simulation instrument. The combustion synthesis process of 15(Ti+C)-65Fe-20Cu (wt%) system, where the molar ratio of Ti to C was 1:1, was studied according to quenching at different temperatures. A four-step model was proposed to describe the combustion synthesis process of Fe-Cu-TiC composites under an electric field. It is suggested that EFACS consists of preheating (I), solid diffusion (II), combustion (III), and post-combustion (IV) stages. The solid diffusion of reactant atoms increases with temperature increasing from the stage I to the stage II. From the stage II to the stage III, carbon atoms gradually diffuse towards titanium atoms until their close contact is performed. During the initial stage III, Ti starts to react with C, i.e. Ti(s) +C(s) =TiC(s) at their interfaces and TiC surrounds the raw Ti atom. Moreover, liquid Cu is formed at the same time. In the following stage III, C atoms diffuse further through the reactant TiC layer, and full reaction between C and Ti is accomplished. The nucleation and growth of TiC takes place in the stage IV. As can be seen from the SEM photographs, TiC exhibits spherical particle.

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張 瑞,馮可芹,孟軍虎,張光明,王海波. Combustion Synthesis of Fe-Cu-TiC Composites under Electric Field[J].稀有金屬材料與工程,2015,44(7):1633~1638.[Zhang Rui, Feng Keqin, Meng Junhu, Zhang Guangming, Wang Haibo. Combustion Synthesis of Fe-Cu-TiC Composites under Electric Field[J]. Rare Metal Materials and Engineering,2015,44(7):1633~1638.]
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  • 收稿日期:2014-07-27
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  • 在線發(fā)布日期: 2016-01-04
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