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剪切帶修復(fù)對Pd基塊體非晶合金腐蝕性能的影響
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煙臺大學(xué),煙臺大學(xué),煙臺大學(xué),煙臺大學(xué),煙臺大學(xué),煙臺大學(xué)

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國家自然科學(xué)基金資助(項目號51101133和51101134),山東省優(yōu)秀中青年科學(xué)家科研獎勵基金(項目號BS2012CL036),山東省自然科學(xué)基金(項目號ZR2011EL025)


Self-healing Effect on the Corrosion Resistance of the Pd-based Amorphous Alloys
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Yantai University,,,,,Yantai University

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    摘要:

    摘 要:本文以Pd79Cu4Au2Si10P5塊體非晶合金為研究對象,采用電化學(xué)極化曲線和電化學(xué)阻抗測試方法研究了剪切帶自修復(fù)對其在3 wt.% NaCl溶液和1 mol/L HCl溶液中耐蝕性能的影響。通過研究極化曲線中的自腐蝕電位和自腐蝕電流密度得知,修復(fù)后樣品耐腐蝕性能優(yōu)于修復(fù)前樣品,但仍低于原始樣品(即未變形樣品)。電化學(xué)阻抗研究結(jié)果顯示,在開路電位下阻抗圖均有單一容抗弧構(gòu)成,修復(fù)后樣品的電化學(xué)轉(zhuǎn)移電阻Rt小于原始樣品的、但大于修復(fù)前樣品的,這進一步表明修復(fù)提高了材料的耐腐蝕性能,但仍未達到原始樣品的耐蝕性。掃描電鏡研究發(fā)現(xiàn),合金表面發(fā)生明顯的點蝕,其中原始樣品的點蝕坑密度最少,修復(fù)后樣品的次之,修復(fù)前樣品的最多。

    Abstract:

    Abstract:The self-healing effect on corrosion behaviors of Pd79Cu4Au2Si10P5 amorphous alloy in 3 wt.% NaCl and 1 mol/L HCl solutions was studied by potentiodynamic polarization experiments and electrochemical impedance spectroscopy (EIS). The results of potentiodynamic polarization experiments show that the self-healing sample has better corrosion resistance than the unrepaired sample, but the as-cast sample has the best corrosion resistance. EIS results show that the Nyquist figures of all the studied samples are composed of one single semi-circle in the state of open circuit potential. The repaired sample has a higher charge transfer reaction resistance than the unrepaired sample, and the as-cast sample has the highest charge transfer reaction resistance. This result is accord with that of potentiodynamic polarization. Surface analysis by SEM shows that all the samples are eroded by pitting corrosion. The pitting density on the surface of the as-cast sample is the least, and that of the un-healing sample is the most.

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劉偉,劉麗,宋賀,熊珊,杜偉,趙相金.剪切帶修復(fù)對Pd基塊體非晶合金腐蝕性能的影響[J].稀有金屬材料與工程,2017,46(10):3053~3057.[LiuWei, Liu Li, Song He, Xiong Shan, Du Wei, Zhao Xiangjin. Self-healing Effect on the Corrosion Resistance of the Pd-based Amorphous Alloys[J]. Rare Metal Materials and Engineering,2017,46(10):3053~3057.]
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  • 收稿日期:2015-06-24
  • 最后修改日期:2015-08-23
  • 錄用日期:2015-10-13
  • 在線發(fā)布日期: 2017-12-01
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