3 /Ga3 雙摻雜的石榴石型Yb3-xGdxAl5-xGaxO12固溶體陶瓷材料 (x=0.0,0.1,0.2,0.3,0.4,0.5;YGAGO)。結(jié)果表明:Gd3 /Ga3 共摻雜的YGAGO保持了石榴石相結(jié)構(gòu);隨著Gd3 /Ga3 摻雜量的增加,固溶體樣品的衍射峰位整體向低角度偏移;SEM形貌表明Yb3Al5O12材料的微觀形貌由納米級(jí)晶粒和高密度晶界構(gòu)成;大離子Gd3 與Ga3 分別對(duì)Yb3Al5O12晶體結(jié)構(gòu)中Yb3 與Al3 晶格位的取代,不僅因引入的點(diǎn)缺陷明顯降低了材料的熱導(dǎo)率,同時(shí)還造成石榴石型Yb3Al5O12晶體結(jié)構(gòu)的松弛,利于熱膨脹系數(shù)的提高。隨著Gd3 /Ga3 摻雜量的增加,晶體中點(diǎn)缺陷濃度不斷升高,聲子平均自由程不斷減小,使得YGAGO的熱導(dǎo)率在x=0.5時(shí)達(dá)到最低值(λ=1.67W/m.K,T=1273K),熱膨脹系數(shù)達(dá)到最高值(ɑl=11.71×10-6 K-1,T=1273K)。"/>

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Gd3 /Ga3 共摻雜石榴石型Yb3Al5O12材料的制備及熱物理性能
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內(nèi)蒙古科技大學(xué)數(shù)理生學(xué)院,內(nèi)蒙古科技大學(xué)數(shù)理生學(xué)院

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Preparation and Thermo-Physical Properties of Gd3 /Ga3 Co-doped Garnet-type Yb3Al5O12
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School of Mathematics,Physics and Biological Engineering,Inner Mongolia University of Science and Technology,School of Mathematics,Physics and Biological Engineering,Inner Mongolia University of Science and Technology

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    摘要:

    采用檸檬酸溶膠-凝膠法制備了Gd3 /Ga3 雙摻雜的石榴石型Yb3-xGdxAl5-xGaxO12固溶體陶瓷材料 (x=0.0,0.1,0.2,0.3,0.4,0.5;YGAGO)。結(jié)果表明:Gd3 /Ga3 共摻雜的YGAGO保持了石榴石相結(jié)構(gòu);隨著Gd3 /Ga3 摻雜量的增加,固溶體樣品的衍射峰位整體向低角度偏移;SEM形貌表明Yb3Al5O12材料的微觀形貌由納米級(jí)晶粒和高密度晶界構(gòu)成;大離子Gd3 與Ga3 分別對(duì)Yb3Al5O12晶體結(jié)構(gòu)中Yb3 與Al3 晶格位的取代,不僅因引入的點(diǎn)缺陷明顯降低了材料的熱導(dǎo)率,同時(shí)還造成石榴石型Yb3Al5O12晶體結(jié)構(gòu)的松弛,利于熱膨脹系數(shù)的提高。隨著Gd3 /Ga3 摻雜量的增加,晶體中點(diǎn)缺陷濃度不斷升高,聲子平均自由程不斷減小,使得YGAGO的熱導(dǎo)率在x=0.5時(shí)達(dá)到最低值(λ=1.67W/m.K,T=1273K),熱膨脹系數(shù)達(dá)到最高值(ɑl=11.71×10-6 K-1,T=1273K)。

    Abstract:

    Gd3 and Ga3 co-doped garnet-type Yb3-xGdxAl5-xGaxO12 solid solution (x=0.0,0.1,0.2,0.3,0.4,0.5;YGAGO) ceramic materials were synthesized by citric acid sol-gel method. XRD results demonstrate that all the Yb3-xGdxAl5-xGaxO12 compositions are comprised of the pure garnet Yb3Al5O12 phase. Increasing the Gd3 and Ga3 doping fractions leads to a shift of the X-ray spectrum to lower 2θ values. SEM morphology shows that microstructure is composed of nano-sized crystal grains and high densed grain boundary. The substitution of larger Gd3 and Ga3 in smaller Yb3 and Al6 sites, respectively, not only can lower the thermal conductivity, but also jontly facilitate higher coefficients of thermal expansion (CET), which is due to the relaxation of distored Yb3-xGdxAl5-xGaxO12 structure with substitutional point defects. The phonon mean free path of Yb3-xGdxAl5-xGaxO12 ceramics decreases with increasing Gd3 and Ga3 fraction at identical temperature levels, which is due to the lattice distortion and local imperfection scaling generated by incorporating large dopant Gd3 and Ga3 cations. Gd3 and Ga3 co-doped garnet-type Yb3-xGdxAl5-xGaxO12 composition showed a minimum thermal conductivity value (λ=1.67W/m.K,T=1273K) and a maximum CET (ɑl=11.71×10-6 K-1,T=1273K) at the composition Yb2.5Gd0.5Al4.5Ga0.5O12.

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李劍生,劉艷麗. Gd3 /Ga3 共摻雜石榴石型Yb3Al5O12材料的制備及熱物理性能[J].稀有金屬材料與工程,2017,46(3):802~806.[Li Jiansheng, Liu Yanli. Preparation and Thermo-Physical Properties of Gd3 /Ga3 Co-doped Garnet-type Yb3Al5O12[J]. Rare Metal Materials and Engineering,2017,46(3):802~806.]
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  • 收稿日期:2015-06-05
  • 最后修改日期:2015-12-15
  • 錄用日期:2016-01-14
  • 在線發(fā)布日期: 2017-05-18
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