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摻鑭方式對(duì)La-TZM合金性能的影響
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陜西省“13115”科技創(chuàng)新工程重大科技專項(xiàng)項(xiàng)目(2008ZDKG-41);陜西省教育廳專項(xiàng)項(xiàng)目(12JK0431)


Effect of Lanthanum Doping Method on Properties of La-TZM Alloy
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    摘要:

    采用粉末冶金法在TZM合金的基礎(chǔ)上,分別進(jìn)行固-固摻雜稀土La2O3,固-液摻雜La(NO3)3,經(jīng)燒結(jié)、熱軋、溫軋、冷軋后得到不同摻雜方式的La-TZM合金板材。用SEM觀察粉末形貌、燒結(jié)坯組織及板材斷口形貌,用粒度分布、EDS分別對(duì)合金粉末粒度及合金成分進(jìn)行分析。結(jié)果表明:固-液摻雜La(NO3)3比固-固摻雜稀土La2O3的La-TZM合金板材第二相分布更為均勻、細(xì)??;晶粒尺寸較?。磺夜?液摻雜La(NO3)3合金的抗拉強(qiáng)度比固-固摻雜稀土La2O3也有顯著提高,使其提高了10.9%。

    Abstract:

    Based on TZM molybdenum alloy, La-TZM alloy sheets, with solid-solid doping of rare earth La2O3 or liquid-solid doping of La(NO3)3, were manufactured by sintering, hot rolling, warm rolling and cold rolling. The powder morphology, microstructures of sintering compact and fracture morphology of the alloy sheets were observed by SEM, and the alloy powder particle size and alloy composition were analyzed by particle size distribution and EDS, respectively. The results show that the distribution of the second phase in the La(NO3)3 doped TZM alloy sheets is more uniform than that in La2O3 doped TZM alloy sheets. The grain size of La(NO3)3 doped TZM alloy is finer. Besides, the tensile strength of La(NO3)3 doped TZM alloy is much higher than that of La2O3 doped alloy, which increases by 10.9%.

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康軒齊,王快社,張 鄭,胡 平,何歡承,劉仁智,王鵬洲.摻鑭方式對(duì)La-TZM合金性能的影響[J].稀有金屬材料與工程,2015,44(5):1254~1258.[Kang Xuanqi, Wang Kuaishe, Zhang Zheng, Hu Ping, He Huancheng, Liu Renzhi, Wang Pengzhou. Effect of Lanthanum Doping Method on Properties of La-TZM Alloy[J]. Rare Metal Materials and Engineering,2015,44(5):1254~1258.]
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  • 收稿日期:2014-05-11
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  • 在線發(fā)布日期: 2015-06-08
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