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NiAl-W共晶定向凝固組織控制與W介納米絲形貌
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西北工業(yè)大學 機電學院

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國家自然科學基金資助(項目號51374173)


The Microstructure Control of NiAl-W Eutectic Directional Solidification and the Morphology of W Meso-nanowires
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Northwestern Polytechnical University

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National Natural Science Foundation of China (30970781); Ph. D. Programs Foundation of Ministry of Education of China (20100181110002); Scientific Research Foundation of Sichuan University for Young Teachers (2012SCU11052)

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    摘要:

    在300 K/cm 的溫度梯度條件下,實施不同抽拉速率下的NiAl-1.5at%W共晶合金定向凝固,分析研究抽拉速率對W纖維相相間距、纖維相尺寸的影響規(guī)律,并使用鹽酸雙氧水溶液對NiAl基體進行選擇性溶解,制備出當量直徑小于500nm的鎢纖維絲束。研究結果表明:隨著抽拉速率的增大,W纖維相截面形狀圓度增加, W纖維相相間距和W纖維相截面當量直徑均減小,兩者的比值在6.12到7.54之間,經(jīng)選擇性溶解獲得W纖維具有多樣的三維形貌,呈現(xiàn)出薄帶狀、珍珠串狀和搭接狀,發(fā)現(xiàn)其形貌與抽拉速率有關。

    Abstract:

    Under a temperature gradient of 300 K/cm, NiAl-1.5at%W eutectic samples were directionally solidified at the different drawing rates to analyze the effect of the drawing rates on the spacing and the size of W fiber phases. Moreover. the NiAl matrix was selectively etched by using a solution of HCl:H2O2 to prepare the tunsten fiber filaments with the equivalent diameter less than 500 nm. The research results show that the roundness of W fiber phase cross-section increases, the spacing and the equivalent diameter of W fiber phase both decreases, the ratio between them is in the range of 6.12 to 7.54, as increasing the drawing rate; and that the tungsten fibers obtained by selective dissolution have the diversiform three-dimensional morphologies, such as the thin strip, pearl string and lapping state, which have been found that those shapes have a relationship with the drawing rate.

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任海果,王文佳,高建軍,閻光明,趙志龍. NiAl-W共晶定向凝固組織控制與W介納米絲形貌[J].稀有金屬材料與工程,2016,45(1):222~226.[Ren Haiguo, Wang Wenjia, Gao Jianjun, Yan Guangming, Zhao Zhilong. The Microstructure Control of NiAl-W Eutectic Directional Solidification and the Morphology of W Meso-nanowires[J]. Rare Metal Materials and Engineering,2016,45(1):222~226.]
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  • 收稿日期:2015-04-14
  • 最后修改日期:2015-09-14
  • 錄用日期:2015-10-13
  • 在線發(fā)布日期: 2019-01-04
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