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Zn摻雜對(duì)LiNi1/3Co1/3Mn1/3O2結(jié)構(gòu)與電化學(xué)性能的影響
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Effect of Zn Doping on the Structure and Electrochemical Performance of LiNi1/3Co1/3Mn1/3O2
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    摘要:

    用溶膠凝膠法制備了LiNi1/3Co1/3-xMn1/3ZnxO2(x=0,1/24,2/24,4/24)鋰離子電池正極材料。由X射線衍射和掃描電鏡對(duì)其分析結(jié)果表明,Zn 摻雜不改變LiNi1/3Co1/3Mn1/3O2的α-NaFeO2層狀結(jié)構(gòu),當(dāng)摻雜量達(dá)到4/24時(shí),雜相產(chǎn)生。電化學(xué)研究表明,當(dāng)Zn摻雜量為2/24時(shí),LiNi1/3Co1/3Mn1/3O2首次放電容量由未摻雜的169.2 mAh·g-1 降低為160.1 mAh·g-1,但循環(huán)性能明顯提高,30次循環(huán)后的容量保持率由未摻雜的89.2%升至97%。并且在20、40、60和80 mA·g-1不同的電流密度下繼續(xù)循環(huán)20次后,當(dāng)再次恢復(fù)到20 mA·g-1的電流密度時(shí),放電容量可恢復(fù)到150.3 mAh·g-1。

    Abstract:

    LiNi1/3Co1/3-xMn1/3ZnxO2 (x=0, 1/24, 2/24 and 4/24) cathode material for lithium-ion battery was synthesized by a sol-gel method. The results of XRD and SEM show that Zn doping does not change the α-NaFeO2 layer structure of LiNi1/3Co1/3Mn1/3O2, and impurity phases occur when the doped amount reaches 4/24. Electrochemical studies indicate that when the doped Zn content is 2/24, the initial discharge capacity of LiNi1/3Co1/3Mn1/3O2 decreases from 169.2 mAh·g-1 of the undoped material to 160.1 mAh·g-1. The cycling performance, however, is significantly improved. Compared with undoped material, the capacity retention rate of the sample of LiNil/3Col/3-xMnl/3ZnxO2 with x=2/24 increases from 89.2% to 97% after 30 cycles. The same sample was charged and discharged again at 20 mA·g?1 and the corresponding discharge specific capacity was restored to 150.3 mAh·g?1 after 20 cycles in different current densities of 20, 40, 60 and 80 mA·g-1.

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毛新鈺,梁小平,劉 建,李冬梅,左 蕊,劉 鎧,羅大軍,王瑞雪. Zn摻雜對(duì)LiNi1/3Co1/3Mn1/3O2結(jié)構(gòu)與電化學(xué)性能的影響[J].稀有金屬材料與工程,2015,44(3):743~747.[Mao Xinyu, Liang Xiaoping, Liu Jian, Li Dongmei, Zuo Rui, Liu Kai, Luo Dajun, Wang Ruixue. Effect of Zn Doping on the Structure and Electrochemical Performance of LiNi1/3Co1/3Mn1/3O2[J]. Rare Metal Materials and Engineering,2015,44(3):743~747.]
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  • 收稿日期:2014-03-18
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  • 在線發(fā)布日期: 2015-05-29
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