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(Nd0.7Pr0.3)60-xFe30Al10Cux (x=0, 1, 2, 4)大塊非晶合金磁性及矯頑力機(jī)理
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國家自然科學(xué)基金(51071099,51171101);上海市教委“085”項(xiàng)目


Magnetic Properties and Coercivity Mechanism in the (Nd0.7Pr0.3)60-xFe30Al10Cux (x=0, 1, 2, 4) Bulk Amorphous Alloys
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    摘要:

    采用銅模吸鑄法制備了(Nd0.7Pr0.3)60-xFe30Al10Cux (x=0, 1, 2 , 4)大塊非晶合金,利用振動(dòng)樣品磁強(qiáng)計(jì)(VSM)研究了該合金的磁性能和磁粘滯行為。結(jié)果表明, 這幾種合金都呈現(xiàn)出較好的硬磁性。隨著Cu元素的添加,矯頑力略有增加,但是合金的剩磁卻沒有變化。利用掃描速率法研究了(Nd0.7Pr0.3)60-xFe30Al10Cux (x=0, 1, 2, 4)大塊非晶合金的磁粘滯行為,得到了這幾種合金的相關(guān)磁性參數(shù):熱擾動(dòng)場Hf為12.1~15.2 mT,熱激活體積va為1.5×10-18~1.9×10-18 cm3。在所研究的合金中都存在明顯的鐵磁交換耦合作用,同時(shí)矯頑力與溫度之間的關(guān)系符合Gaunt提出的疇壁釘扎模型,合金的硬磁性可能是這兩方面共同作用的結(jié)果。

    Abstract:

    Bulk amorphous (Nd0.7Pr0.3)60-xFe30Al10Cux (x=0, 1, 2 , 4) alloys with diameter of 2 mm were prepared by argon arc melting and suction casting the molten alloy into a copper mould. The magnetic properties and coercivity mechanism of the alloys were investigated by the measurement of major hysteresis loop, exchange coupling curve (dM-H plot), magnetic viscosity and the temperature dependence of the coercivity. At room temperature, all the alloys exhibit hard magnetic properties. The coercivity increases slightly with increasing the Cu content, while the remanence has the same values. The fluctuation field, Hf, is determined from sweep rate measurement. It is in the range of 12.1~15.2 mT. The thermal activation volume, va, is from 1.5×10-18 to 1.9×10-18 cm3. The exchange coupling interaction in all four alloys is confirmed by the dM-H plot. The temperature dependence of the coercivity can be well explained by Gaunt’s strong pinning model of domain walls. The hard magnetic behavior of bulk amorphous (Nd0.7Pr0.3)60-xFe30Al10Cux (x=0, 1, 2, 4) alloys may be determined by the exchange coupling interaction among clusters and strong domain wall pinning.

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唐永軍,徐 暉,侯雪玲.(Nd0.7Pr0.3)60-xFe30Al10Cux (x=0, 1, 2, 4)大塊非晶合金磁性及矯頑力機(jī)理[J].稀有金屬材料與工程,2015,44(3):634~637.[Tang Yongjun, Xu Hui, Hou Xueling. Magnetic Properties and Coercivity Mechanism in the (Nd0.7Pr0.3)60-xFe30Al10Cux (x=0, 1, 2, 4) Bulk Amorphous Alloys[J]. Rare Metal Materials and Engineering,2015,44(3):634~637.]
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  • 收稿日期:2014-03-16
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  • 在線發(fā)布日期: 2015-05-29
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