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先進單晶高溫合金均勻化-固溶熱處理的研究與設(shè)計
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北京航空材料研究院先進高溫結(jié)構(gòu)材料重點實驗室,北京航空材料研究院先進高溫結(jié)構(gòu)材料重點實驗室,北京航空材料研究院先進高溫結(jié)構(gòu)材料重點實驗室,北京航空材料研究院先進高溫結(jié)構(gòu)材料重點實驗室

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Designing of the Homogenization-Solution Heat Treatment for Advanced Single Crystal Superalloys
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Science and Technology on Advanced High Temperature Structural Materials Laboratory,Beijing Institute of Aeronautical Materials,Science and Technology on Advanced High Temperature Structural Materials Laboratory,Beijing Institute of Aeronautical Materials,Science and Technology on Advanced High Temperature Structural Materials Laboratory,Beijing Institute of Aeronautical Materials,Science and Technology on Advanced High Temperature Structural Materials Laboratory,Beijing Institute of Aeronautical Materials

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National Key Basic Research Program of China (“973” Program) (2011CBA00104); the International Scientific and Technological Cooperation Projects of China (S2010GR0518); the National Natural Science Foundation of China (51102198)

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    摘要:

    為設(shè)計更適用于先進單晶高溫合金的均勻化-固溶熱處理制度,研究了不同熱處理溫度和時間對一種先進單晶高溫合金組織的影響。使用金相顯微鏡和場發(fā)射電子顯微鏡觀察合金組織,使用電子探針測試合金元素分布,并分析試驗結(jié)果。試驗發(fā)現(xiàn),當溫度直接升至γ′相溶解的實際起始溫度1338℃時,合金不會發(fā)生初熔;當溫度直接升至γ′相溶解的外推初始溫度1350℃時,合金中出現(xiàn)了明顯初熔,但初熔組織隨著保溫時間的延長逐漸減少;當溫度直接升至較低的1328℃時,合金中雖然沒有發(fā)生初熔,但均勻化效率明顯降低。結(jié)合先進單晶高溫合金高熔點元素含量較高的特點對試驗結(jié)果進行熱力學和動力學計算與分析,結(jié)果表明,單晶高溫合金的均勻化-固溶熱處理窗口是一個動態(tài)的窗口,γ′相完全溶解溫度和初熔溫度均隨著合金均勻化程度的提高而提高;高代單晶高溫合金在均勻化-固溶熱處理中,不須要將溫度始終保持在鑄態(tài)合金的初熔溫度以下,只要保證溫度低于合金所在均勻化狀態(tài)對應(yīng)的初熔溫度即可;均勻化-固溶熱處理中,提高每一臺階的溫度可以得到的均勻化-固溶效果遠優(yōu)于延長熱處理時間可達到的效果。根據(jù)試驗及分析結(jié)果提出了一種適用于先進單晶高溫合金的均勻化-固溶熱處理制度設(shè)計方法,使試驗合金在較短時間內(nèi)得到了理想的合金組織和均勻化效果。

    Abstract:

    To design more efficient homogenization-solution heat treatments for advanced single crystal superalloys, an experimental single crystal superalloy was studied after homogenization-solution heat treatments with different temperatures and durations. Metallographic and field emission microscope were used to observe microstructures; electron probe was applied for component analysis. The results show that no incipient melting appears when the alloy is directly heated up to 1338℃; when it is directly heated up to 1350℃, obvious incipient melting occurs, while the incipient melting microstructure gradually fades away with holding time; for an lower temperature 1328℃, although there is no risk of incipient melting, the homogenization-solution efficiency is far from satisfactory. After analyzing the results by aid of dynamics and thermodynamics calculation, it can be concluded that the single crystal superalloy owns a dynamic homogenization-solution heat treatment window: both the γ′ solvus end temperature and the incipient melting temperature increase with the homogenization process. Such dynamic characteristic is especially noticeable for advanced single crystal superalloys since the segregation is more severe. There is no need to always keep the homogenization-solution heat treatment temperature below the incipient melting temperature of the as-cast condition, but keeping it below the incipient melting temperature of the alloy at the temporal homogenous state is necessary. For advanced single crystal superalloys, elevating temperatures of each step is much more effective than prolonging duration to get better heterogeneous effect. By using above conclusions, a new approach is introduced to design effective homogenization-solution heat treatments for advanced single crystal superalloys, and it has been successfully used on the experimental single crystal superalloy.

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岳曉岱,李嘉榮,史振學,王效光.先進單晶高溫合金均勻化-固溶熱處理的研究與設(shè)計[J].稀有金屬材料與工程,2017,46(6):1530~1535.[Yue Xiaodai, Li Jiarong, Shi Zhenxue, Wang Xiaoguang. Designing of the Homogenization-Solution Heat Treatment for Advanced Single Crystal Superalloys[J]. Rare Metal Materials and Engineering,2017,46(6):1530~1535.]
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  • 收稿日期:2015-03-25
  • 最后修改日期:2015-07-14
  • 錄用日期:2015-10-13
  • 在線發(fā)布日期: 2017-11-07
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