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激光偏移量對Hastelloy C-276/316L焊縫腐蝕性能的影響
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國家重點基礎研究發(fā)展計劃(2009CB724307);國家自然科學基金(51175061)


Effects of Laser Offset on the Corrosion Performance
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    摘要:

    使用Nd:YAG連續(xù)激光對Hastelloy C-276/316L薄板進行異質(zhì)焊接實驗,分析不同激光偏移量下焊縫元素含量變化規(guī)律,借助極化曲線、電化學阻抗譜研究不同激光偏移量下焊縫在鹽酸溶液中的抗蝕性能。結(jié)果表明:調(diào)節(jié)激光偏移量Fe、Ni和Mo含量變化明顯,而Cr含量無明顯變化;當激光向Hastelloy C-276偏移0.1~0.3 mm時,焊縫中主要元素含量變化較小,腐蝕電壓、電荷轉(zhuǎn)移電阻最大,腐蝕電流密度最小,焊縫腐蝕趨勢、腐蝕速率最小,焊縫抗蝕性能較好;當激光向316L偏移0至0.2 mm時,焊縫中Fe元素逐漸增加,Ni、Mo元素含量逐漸下降,焊縫的腐蝕電壓、電荷轉(zhuǎn)移電阻遞減,腐蝕電流密度遞增,焊縫的腐蝕趨勢、腐蝕速率逐漸增大,焊縫抗蝕性逐漸減弱

    Abstract:

    Dissimilar welding experiments of Hastelloy C-276/316L thin sheet was performed by Nd:YAG continuous laser. The element content changes of the weld under different laser offsets were studied and the effects of laser offset on the corrosion performance of Hastelloy C-276/316L weld in HCL solution were also investigated by means of polarization curves and electrochemical impedance spectroscopy. The results show that Ni, Fe and Mo contents change significantly with adjusting the laser offset, while Cr element content has no obvious change. When the laser offset is between 0.1~0.3 mm, the main element contents in the weld change slightly, the corrosion voltage and the charge transfer resistance are the largest and the corrosion current density is minimal. At this time the corrosion trend and the corrosion rate of the weld is minimum. Therefore, the corrosion resistance of the weld is the best under this parameter. When the laser offset changes from 0 to –0.2 mm, the content of Fe in the weld increases gradually, but the contents of Ni and Mo decrease. It is the main cause of the decrement of corrosion voltage and the charge transfer resistance. Corrosion current density increases and the corrosion trend as well as the corrosion rate of the weld increase gradually. As a result, the corrosion resistance of weld shows a trend of weakening under this parameter

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吳東江,范 聰,劉士博,馬廣義,郭玉泉,牛方勇,郭東明.激光偏移量對Hastelloy C-276/316L焊縫腐蝕性能的影響[J].稀有金屬材料與工程,2015,44(2):498~502.[Wu Dongjiang, Fan Cong, Liu Shibo, Ma Guangyi, Guo Yuquan, Niu Fangyong, Guo Dongming. Effects of Laser Offset on the Corrosion Performance[J]. Rare Metal Materials and Engineering,2015,44(2):498~502.]
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  • 收稿日期:2014-01-02
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  • 在線發(fā)布日期: 2015-05-29
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