2O3二次相粒子的形式均勻彌散分布于W晶粒的晶內(nèi)和晶界處,能有效抑制W晶粒的長大,顯著細(xì)化晶粒,提高其力學(xué)性能。微量稀土Y的添加改變了W合金的斷裂形式,由純W的沿晶斷裂轉(zhuǎn)變?yōu)橹饕鼐А⒉糠执┚У臄嗔逊绞健?/>

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微量Y增強(qiáng)細(xì)晶W燒結(jié)行為和組織性能的研究
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中南大學(xué) 粉末冶金國家重點(diǎn)實(shí)驗(yàn)室,中南大學(xué) 粉末冶金國家重點(diǎn)實(shí)驗(yàn)室,中南大學(xué) 粉末冶金國家重點(diǎn)實(shí)驗(yàn)室,中南大學(xué) 粉末冶金國家重點(diǎn)實(shí)驗(yàn)室,中南大學(xué) 粉末冶金國家重點(diǎn)實(shí)驗(yàn)室

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TG149.4

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國家自然基金(51474242);國家科技部重大專項(xiàng)(2014GB115000);教育部博士點(diǎn)基金(20130162130002)


Study on Sintering Behavior, Microstructure and Property of trace yttrium enhanced fine -grained W alloy
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State Key Laboratory for Powder Metallurgy,Central South University,State Key Laboratory for Powder Metallurgy,Central South University,State Key Laboratory for Powder Metallurgy,Central South University,State Key Laboratory for Powder Metallurgy,Central South University,State Key Laboratory for Powder Metallurgy,Central South University

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    以“溶膠噴霧干燥-納米原位復(fù)合”合成的超細(xì)/納米W-0.3%Y復(fù)合粉末為原料,通過普通模壓-預(yù)燒和在1800~1950℃下燒結(jié)制備細(xì)晶鎢合金。檢測了合金顯微硬度和拉伸強(qiáng)度,并利用掃描電鏡SEM和X射線能量色散譜(EDX)觀察了斷口形貌及顯微組織,研究其燒結(jié)行為及斷裂行為變化。結(jié)果表明:微量稀土Y以Y2O3二次相粒子的形式均勻彌散分布于W晶粒的晶內(nèi)和晶界處,能有效抑制W晶粒的長大,顯著細(xì)化晶粒,提高其力學(xué)性能。微量稀土Y的添加改變了W合金的斷裂形式,由純W的沿晶斷裂轉(zhuǎn)變?yōu)橹饕鼐?、部分穿晶的斷裂方式?/p>

    Abstract:

    Through the ordinary moulding - presintering, sintering at 1800-1950 ℃,the fine-grained tungsten alloys were fabricated with ultrafine/nano composite powders of W-0.3%Y which were prepared by Sol-spray drying- Nano in situ composite.The microhardness and tensile strength of alloys were detected,Moreover ,Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy were used to examine fracture morphology and microstructure .The evolution of Sintering and Fracture behavior were investigated.The results show that the added trace yttrium exists in the form of Y2O3 as the second phase particles dispersing throughout grain boundary and inner grain of W, restraining tungsten grain growth and making the grains to be significantly refined,which is to improve the mechanical properties of the alloys.Besides,The fracture mode of tungsten alloy with adding trace yttrium was changed from intergranular fracture transition of pure tungsten to mainly intergranular fracture and part transgranular fracture.

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呂永齊,范景蓮,韓勇,劉濤,李鵬飛.微量Y增強(qiáng)細(xì)晶W燒結(jié)行為和組織性能的研究[J].稀有金屬材料與工程,2017,46(6):1704~1708.[Lv Yongqi, Fan Jinglian, Han Yong, Liu Tao, Li Pengfei. Study on Sintering Behavior, Microstructure and Property of trace yttrium enhanced fine -grained W alloy[J]. Rare Metal Materials and Engineering,2017,46(6):1704~1708.]
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  • 收稿日期:2015-02-06
  • 最后修改日期:2015-07-30
  • 錄用日期:2015-11-18
  • 在線發(fā)布日期: 2017-11-07
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