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不同加壓方式下鎂合金微弧氧化膜結(jié)構(gòu)及耐蝕性的變化規(guī)律
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蘭州理工大學 有色金屬先進加工與再利用省部共建國家重點實驗室 蘭州 730050,蘭州理工大學 有色金屬先進加工與再利用省部共建國家重點實驗室 蘭州 730050,蘭州理工大學 有色金屬先進加工與再利用省部共建國家重點實驗室 蘭州 730050,蘭州理工大學 有色金屬先進加工與再利用省部共建國家重點實驗室 蘭州 730050,蘭州理工大學 有色金屬先進加工與再利用省部共建國家重點實驗室 蘭州 730050

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TG174

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甘肅省創(chuàng)新研究群體計劃(1111RJDA011)


Characteristics of microstructure and corrosion resistant of micro arc coatings on magnesium alloy fabricated with different power loading processes
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State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals,Lanzhou University of Technology,State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals,Lanzhou University of Technology,State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals,Lanzhou University of Technology,State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals,Lanzhou University of Technology,State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals,Lanzhou University of Technology

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    摘要:

    硅酸鹽體系電解液中采用恒壓、變壓兩種加壓方式對AZ91D鎂合金進行不同時間的微弧氧化處理,研究膜層的厚度、表面形貌、物相組成及耐蝕性隨時間的變化規(guī)律,對膜層中微孔的大小、數(shù)量及表面孔隙率進行定量統(tǒng)計,比較兩加壓方式下膜層的差異。結(jié)果表明:兩加壓方式下,膜層結(jié)構(gòu)隨時間的變化規(guī)律基本相同,其變化幅度變壓方式下相對較大;隨著處理時間的增加,膜層的厚度不斷增大,微孔數(shù)量不斷減少,較大微孔不斷增多,表面孔隙率不斷增大,而物相組成卻不變;膜層的耐蝕性恒壓方式下不斷增強,變壓方式下則先增大后減小;與變壓方式相比,恒壓方式下膜層生長前期的生長速率較大,更有利于工業(yè)化生產(chǎn)。

    Abstract:

    AZ91D magnesium alloys were treated at different time by micro arc oxidation (MAO) in silicate-containing electrolyte. In this work,two types of power loading processes, named P1 mode (constant voltage) and P2 mode (variable voltage ) respectively, were used to prepare the coatings. Varitations of the thickness, surface morphology, phase composition and corrosion resistant of the coatings with treatment time were investigated and the size and amount of the micro pores on coating surface and the surface porosity were studied quantitatively. The results show that the coatings obtained under these two power loading processes had similar evolution patterns in characteristics of microstructure and the extent of which was larger in P2 mode. With prolonging treatment time, the thickness of the coatings was enlarged, with the amount of the total mircro pores and the bigger ones decreasing and increasing, respectively, and the surface porosity of the coatings increased. However, the phase composition of the coatings had no change. The corrosion resistance of the coatings increased continually under P1 mode but it firstly increased and then decreased under P2 mode with treatment time. Comparing these two processes, the P1 mode has an advantage in industrial applications because the MAO coating can grow in a larger rate during the early stage.

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董海榮,馬穎,郭惠霞,王勁松,郝遠.不同加壓方式下鎂合金微弧氧化膜結(jié)構(gòu)及耐蝕性的變化規(guī)律[J].稀有金屬材料與工程,2017,46(6):1656~1661.[DONG Hairong, MA Ying, GUO Huixia, WANG Jinsong, HAO Yuan. Characteristics of microstructure and corrosion resistant of micro arc coatings on magnesium alloy fabricated with different power loading processes[J]. Rare Metal Materials and Engineering,2017,46(6):1656~1661.]
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  • 收稿日期:2015-01-29
  • 最后修改日期:2015-08-10
  • 錄用日期:2015-09-06
  • 在線發(fā)布日期: 2017-11-07
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