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電子束熔煉提純鎢中雜質(zhì)脫除靜態(tài)動(dòng)力學(xué)研究
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國(guó)家自然科學(xué)基金(50774098)


Static Kinetics of Removal of Impurities from Tungsten Melt during Electron Beam Melting
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    摘要:

    研究了電子束熔煉提純鎢過程中典型雜質(zhì)的脫除,考察了電子束熔煉提純鎢的可行性,對(duì)電子束熔煉過程中的除雜動(dòng)力學(xué)進(jìn)行了分析,并確定了110、130、250 kW功率條件下雜質(zhì)Fe、Si、Ti的脫除速率控制機(jī)制。結(jié)果表明:除Mo外,電子束熔煉對(duì)基體鎢中各種雜質(zhì)均有不同程度的脫除,其脫除率與飽和蒸氣壓差存在對(duì)應(yīng)關(guān)系;通過分析并結(jié)合電子束熔煉實(shí)驗(yàn),確定了Si、Fe、Ti在110 kW時(shí)的傳質(zhì)系數(shù)分別為0.21、0.56、0.11×10-4 m/s, 在130 kW時(shí)的傳質(zhì)系數(shù)分別為0.83、3.04、1.78×10-4 m/s, 在250 kW時(shí)的傳質(zhì)系數(shù)分別為0.36、2.37、1.48×10-4 m/s,表明其脫除速率控制機(jī)制均為液/氣界面中的擴(kuò)散。

    Abstract:

    The removal of typical impurity from tungsten using electron beam melting was studied. The feasibility of electron beam melting purification of tungsten was investigated. The impurity removal kinetics of electron beam melting was analyzed, and the removal rate control mechanism of Fe, Si and Ti at the power of 110, 130, and 250 kW was obtained. The results show that various impurities can be removed from the tungsten matrix by electron beam melting except Mo, and the removal efficiency and saturated vapor pressure difference are closely related. Kinetics analysis of removal of impurities and electron beam melting experiment indicate that Si, Fe and Ti is controlled by liquid-gas interface mass transfer with the mass transfer coefficient of 0.21, 0.56, 0.11×10-4m/s at 110 kW, and 0.83, 3.04, 1.78×10-4 m/s at 130 kW, whereas 0.36, 2.37, 1.48×10-4 m/s at 250 kW, respectively.

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劉文勝,龍路平,馬運(yùn)柱,劉 業(yè),劉書華.電子束熔煉提純鎢中雜質(zhì)脫除靜態(tài)動(dòng)力學(xué)研究[J].稀有金屬材料與工程,2015,44(1):113~117.[Liu Wensheng, Long Luping, Ma Yunzhu, Liu Ye, Liu Shuhua. Static Kinetics of Removal of Impurities from Tungsten Melt during Electron Beam Melting[J]. Rare Metal Materials and Engineering,2015,44(1):113~117.]
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  • 收稿日期:2014-01-18
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  • 在線發(fā)布日期: 2015-05-22
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