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鎳基自潤滑涂層的制備及拉伸結(jié)合強度研究
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國家自然科學(xué)基金(51171143,51275386);中央高?;A(chǔ)研究基金以及新世紀(jì)優(yōu)秀人才計劃(NCET-11-0418);國家重點基礎(chǔ)研究發(fā)展計劃(“973”計劃)(2013CB035705)


Synthesis and Tensile Binding Strength of Ni-based Self-lubricating Coatings
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    摘要:

    采用等離子噴涂與粉末冶金方法分別制備了PS304、PM304鎳基自潤滑涂層,并對涂層的組織、拉伸結(jié)合強度進(jìn)行了研究。結(jié)果表明:采用等離子噴涂制備的PS304涂層組織粗大、孔隙率高、潤滑相與強化相分布不均勻。而采用高能球磨與真空燒結(jié)技術(shù)制備的PM304涂層組織均勻、致密、粒子明顯細(xì)化。拉伸試驗表明:PS304的拉伸結(jié)合強度較低,拉伸斷口不僅出現(xiàn)在涂層與基底的結(jié)合處、也出現(xiàn)在涂層內(nèi)部;而PM304的拉伸結(jié)合強度較高,涂層與基底之間結(jié)合良好、結(jié)合方式為冶金結(jié)合,拉伸斷口主要出現(xiàn)在涂層內(nèi)部。PM304涂層拉伸強度增大的原因主要為:(1)致密度提高;(2)尖銳孔隙數(shù)量降低;(3)Ag與NiCr之間形成冶金結(jié)合;(4)NiCr基體中析出粒子的彌散強化作用使得NiCr基體強度提高。

    Abstract:

    The microstructure and tensile binding strength of Ni-based self-lubricating coatings PS304 by plasma spraying and PM304 by powder metallurgy were studied. The result shows that the PS304 coating prepared by plasma-spraying has a coarse microstructure and high porosity. The lubricant phase fluoride and strengthening phase Cr2O3 are distributed unevenly. However, the microstructure of PM304 coating prepared by mechanical milling and vacuum sintering is uniform and dense, and the size of particles is much finer. The tensile test shows that the PS304 coating has a low tensile binding strength. The tensile fracture occurs not only in the interface of coating and substrate, but also appears in the internal of the coating. The PM304 coating has a higher tensile binding strength, and a good metallurgical bonding can be obtained between coating and substrate. The tensile fracture mainly appears in the internal of the coating. The higher tensile binding strength of PM304 coating is mainly due to 4 reasons, including the increase of density, the decrease of the sharp pores number, a metallurgical bonding formed between Ag and NiCr, and the dispersion hardening effect of fine particles precipitated from the NiCr substrate which increases the strength of the NiCr substrate.

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段文博,孫巖樺,丁春華,耿海鵬,戚社苗,虞 烈.鎳基自潤滑涂層的制備及拉伸結(jié)合強度研究[J].稀有金屬材料與工程,2015,44(1):79~84.[Duan Wenbo, Sun Yanhua, Ding Chunhua, Geng Haipeng, Qi Shemiao, Yu Lie. Synthesis and Tensile Binding Strength of Ni-based Self-lubricating Coatings[J]. Rare Metal Materials and Engineering,2015,44(1):79~84.]
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  • 收稿日期:2014-01-27
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  • 在線發(fā)布日期: 2015-05-22
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