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擠壓態(tài)Mg99.2Ca0.6Mn0.2合金的力學(xué)行為及腐蝕性能研究
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西安理工大學(xué),西安理工大學(xué),西安理工大學(xué),西安理工大學(xué),西安理工大學(xué),西安工業(yè)大學(xué)

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陜西省科技計(jì)劃項(xiàng)目(2010K10-08),陜西省教育廳科學(xué)研究計(jì)劃項(xiàng)目(2013JK0906),陜西省光電功能材料與器件重點(diǎn)實(shí)驗(yàn)室項(xiàng)目(ZSKJ201302)和光機(jī)電裝備技術(shù)北京市重點(diǎn)實(shí)驗(yàn)室開(kāi)放課題基金(KF2013-01)資助


Mechanical behavior and corrosion properties of hot extruded Mg99.2Ca0.6Mn0.2 alloy
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Xi’an University of Technology,Xi'an University of Technology,Xi'an University of Technology,Xi'an University of Technology,Xi'an University of Technology,Xi'an Technological University

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    摘要:

    研究了擠壓態(tài)Mg99.2Ca0.6Mn0.2鎂合金的位伸行為和壓縮行為,探討了合金在不同PH值的SBF模擬體液中的電化學(xué)極化曲線和阻抗譜,以評(píng)定合金的腐蝕性能,為鎂合金植入材料的制備提供依據(jù)。結(jié)果表明:擠壓態(tài)Mg99.2Ca0.6Mn0.2合金表現(xiàn)出準(zhǔn)解理斷裂的特征,抗拉強(qiáng)度、屈服強(qiáng)度、延伸率分別為279 MPa、251 MPa和11%,抗壓強(qiáng)度為330 MPa。腐蝕介質(zhì)的PH值對(duì)合金的腐蝕性能有顯著影響。隨著腐蝕介質(zhì)PH值升高,阻抗譜弧半徑大幅度增大,合金的腐蝕電位升高,腐蝕電流密度降低,合金的腐蝕速率明顯下降。在阻抗譜的低頻端出現(xiàn)了一個(gè)時(shí)間常數(shù)。PH值為7.2和10的SBF溶液中的瞬時(shí)腐蝕速率分別為4.1 mm/a和0.2 mm/a。

    Abstract:

    The tensile and compression behavior of hot extruded Mg99.2Ca0.6Mn0.2 (at%) alloy were tested, the cyclic polarization curves and impedance spectroscopy of the alloy soaked in SBF solutions with various pH values were measured by electrochemical method so that the corrosion properties of the alloy can be evaluated and the experimental foundations for preparation of magnesium implant materials is provided. The results show that the tensile failure of the alloy appears to be characteristic of quasi-cleavage fracture, the tensile strength, yield strength, compressive strength and elongation are 279 MPa, 251 MPa, 330 MPa and 11% at room temperature, respectively. The PH value of the solution has prominent effect on corrosion property. As the PH value increases, the arc radius of impedance spectroscopy and corrosion potentials increase remarkably, whereas the corrosion current density decreases, and thus the corrosion resistance of the alloy is strengthened. There is only one time constant which appears in low frequency in phase angle plot. The corrosion rate can be significantly reduced by increasing PH value of the solution. The instantaneous corrosion rates of the alloy immersed in the solutions with PH value of 7.2 and 10.0 are 4.1 mm/a and 0.2 mm/a after, respectively.

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張忠明,馬瑩,任偉偉,王婷,徐春杰,惠增哲.擠壓態(tài)Mg99.2Ca0.6Mn0.2合金的力學(xué)行為及腐蝕性能研究[J].稀有金屬材料與工程,2017,46(9):2352~2358.[Zhang Zhongming, Ma Ying, Ren Weiwei, Wang Ting, Xu Chunjie, Xi Zengzhe. Mechanical behavior and corrosion properties of hot extruded Mg99.2Ca0.6Mn0.2 alloy[J]. Rare Metal Materials and Engineering,2017,46(9):2352~2358.]
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  • 收稿日期:2015-09-07
  • 最后修改日期:2016-11-14
  • 錄用日期:2016-12-02
  • 在線發(fā)布日期: 2017-11-29
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