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碳化鎢模仁表面沉積Re-Ir抗高溫黏連性涂層研究
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北京科技大學(xué)新材料技術(shù)研究院

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TG76

基金項(xiàng)目:

國家自然科學(xué)基金資助(項(xiàng)目號51272024);中央高校基本科研業(yè)務(wù)費(fèi)資助(項(xiàng)目號FRF-TP-14-094A2);教育部博士點(diǎn)基金資助(項(xiàng)目號20110006110011)


Study of antistick Re-Ir protective coating on WC mould substrate
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北京科技大學(xué)新材料技術(shù)研究院

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    摘要:

    超精密(納米精度)模仁是模造技術(shù)制備玻璃鏡片的核心部件,而模仁表面的保護(hù)涂層則決定著模仁的使用壽命及玻璃制件的成型質(zhì)量與成本。本研究采用射頻磁控濺射技術(shù),在WC模仁基材表面分別鍍制Re、Ir單層膜及Re/Ir復(fù)合多層膜三種膜系。通過掃描電子顯微鏡、表面輪廓儀、X射線衍射儀以及納米壓痕儀等對所制備涂層的表面形貌、結(jié)構(gòu)以及涂層力學(xué)性能進(jìn)行表征,同時(shí)采用高溫潤濕角測量儀結(jié)合常用的鏡頭玻璃硝材D-ZK3與模仁進(jìn)行高溫浸潤測試。結(jié)果表明,涂覆三種膜系后模仁力學(xué)性能及抗玻璃高溫黏連性能都得到了明顯改善,且Re/Ir多層膜系綜合性能優(yōu)于Re和Ir單層膜系,在延續(xù)基材表面精度的同時(shí),較大幅度地提高了模仁表面硬度及彈性模量,高溫狀態(tài)下與玻璃硝材浸潤性明顯減弱,接觸界面未觀察到元素互擴(kuò)散現(xiàn)象,顯示良好的應(yīng)用前景。

    Abstract:

    Precision glass moulding is a replicative process that allows the production of high precision optical components from glass without grinding and polishing. In order to enhance the mould insert"s lifetime, protective coatings can be applied. In this study, Re, Ir monolayer and Re/Ir multilayer were deposited on the WC substrate by RF magnetron sputtering deposition system respectively. SEM, XRD, Nano Indenter and contour graph were used to characterize those protective coatings. The wetting angle at high temperature was adopted to evaluate the sticking situation between mould and D-ZK3 glass. The results demonstrated that the mechanical property and antistick performance of the mould after coating were both improved significantly. Re/Ir multilayer shows best antistik capability as well as mechanical property among these three types of coating. Meanwhile, the glass after wetting contact test with Re/Ir multilayer coating still have high transparency, which demonstrate that almost no interfacial reaction between glass gob and protective coating happened. This study displays a promising application of Re/Ir multilayer protective coating in glass moulding technology.

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引用本文

魏俊俊,朱小研,陳良賢,劉金龍,黑立富,李成明.碳化鎢模仁表面沉積Re-Ir抗高溫黏連性涂層研究[J].稀有金屬材料與工程,2016,45(1):227~231.[Wei Junjun, Zhu Xiaoyan, Cheng Liangxian, Liu Jinlong, Hei Lifu, Li Chengming. Study of antistick Re-Ir protective coating on WC mould substrate[J]. Rare Metal Materials and Engineering,2016,45(1):227~231.]
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  • 收稿日期:2014-12-16
  • 最后修改日期:2015-05-29
  • 錄用日期:2015-08-11
  • 在線發(fā)布日期: 2019-01-04
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