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低溫磁控濺射制備AZO薄膜及絨面研究
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浮法玻璃新技術(shù)國家重點(diǎn)實(shí)驗(yàn)室;蚌埠玻璃工業(yè)設(shè)計(jì)研究院,浮法玻璃新技術(shù)國家重點(diǎn)實(shí)驗(yàn)室;蚌埠玻璃工業(yè)設(shè)計(jì)研究院,浮法玻璃新技術(shù)國家重點(diǎn)實(shí)驗(yàn)室;蚌埠玻璃工業(yè)設(shè)計(jì)研究院,浮法玻璃新技術(shù)國家重點(diǎn)實(shí)驗(yàn)室;蚌埠玻璃工業(yè)設(shè)計(jì)研究院,浮法玻璃新技術(shù)國家重點(diǎn)實(shí)驗(yàn)室;蚌埠玻璃工業(yè)設(shè)計(jì)研究院,浮法玻璃新技術(shù)國家重點(diǎn)實(shí)驗(yàn)室;蚌埠玻璃工業(yè)設(shè)計(jì)研究院

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O484.4

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中國建筑材料集團(tuán)有限公司集團(tuán)經(jīng)費(fèi)資助


Study on Preparation and Their Textured Structures of AZO Thin Films by Magnetron Sputtering at Low Temperature
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State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry,State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry,State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry,State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry,State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry,State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry

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    本文采用直流射頻耦合磁控濺射技術(shù),以AZO(2 wt % Al2O3 )陶瓷靶為靶材,在玻璃基片上低溫沉積AZO薄膜,并采用質(zhì)量分?jǐn)?shù)為0.5%的HCl溶液刻蝕制備絨面AZO薄膜,通過XRD、SEM、分光光度計(jì)、霍爾效應(yīng)測試系統(tǒng)、光電霧度儀等設(shè)備重點(diǎn)研究工作壓強(qiáng)對直流射頻耦合磁控濺射制備AZO薄膜的晶相結(jié)構(gòu)、表面形貌、光電性能以及后期制絨的影響。研究表明,直流射頻耦合磁控濺射可以在低溫下制備性能優(yōu)異的AZO薄膜,且隨著工作壓強(qiáng)的減少,致密性增加,光電性能改善,后期刻蝕得到具有良好陷光作用的絨面結(jié)構(gòu)。在工作壓強(qiáng)0.5Pa下,低溫制備的AZO薄膜電阻率達(dá)到3.55?0-4Ω?cm,薄膜可見光透過達(dá)到88.36%,刻蝕后電阻率為4.19?0-4Ω?cm,可見光透過率89.59%,霧度達(dá)24.7%。

    Abstract:

    The AZO films were deposited on glass substrates by DC coupled RF magnetron sputtering at low temperature with a AZO ceramic target(2 wt % Al2O3) , and then AZO films were etched by the mass fraction of 0.5% HCl solution to obtain textured structures. Crystal phase structure, surface morphology, optical, electrical properties and the textured structure of AZO films mainly influenced by working pressure were characterized by XRD, SEM, spectrophotometer, hall effect test system and photoelectric haze instrument respectively. The results show that AZO thin films with excellent performance can be prepared by DC coupled RF magnetron sputtering at low temperatures. With the decrease of working pressure, the compactness of AZO films is increased, and their photoelectric performance improves, and textured structures with good light trapping effect can be obtained by post etching. Under working pressure of 0.5 Pa, the resistivity of AZO thin films prepared at low temperature is 3.55?0-4 Ω?cm, and the transmittance at visible light is 88.36%. After etching, their resistivity and transmittance at visible light are 4.19?0-4 Ω?cm and 89.59% respectively, and the haze reaches to 24.7%.

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張寬翔,彭壽,姚婷婷,曹欣,金克武,徐根保.低溫磁控濺射制備AZO薄膜及絨面研究[J].稀有金屬材料與工程,2017,46(3):818~823.[Zhang Kuanxiang, Peng Shou, Yao Tingting, Cao Xin, Jin Kewu, Xu Genbao. Study on Preparation and Their Textured Structures of AZO Thin Films by Magnetron Sputtering at Low Temperature[J]. Rare Metal Materials and Engineering,2017,46(3):818~823.]
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  • 收稿日期:2014-11-24
  • 最后修改日期:2014-12-18
  • 錄用日期:2015-03-25
  • 在線發(fā)布日期: 2017-05-18
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