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等離子噴涂YSZ熱障涂層樁釘結構激光表面改性
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華南理工大學,廣州有色金屬研究院

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The peg-nail structure selective laser modification of plasma sprayed YSZ thermal barrier coatings
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South China University of Technology,Guangzhou Research Institute of Non-ferrous Metals

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    摘要:

    實驗采用大氣等離子噴涂技術在鎳基高溫合金基體表面制備了ZrO2-7%Y2O3 熱障涂層,利用Nd:YAG脈沖激光對YSZ涂層進行樁釘結構選擇性激光表面改性。重點考察樁釘結構激光表面改性對涂層的組織結構和性能的影響。結果顯示,樁釘結構激光表面改性有助于降低涂層表面的粗糙度,消除表面的孔隙,產(chǎn)生了垂直于表面的網(wǎng)狀裂紋。樁釘結構激光改性區(qū)域的橫截面出現(xiàn)柱狀晶及等軸晶結構。XRD分析表明,噴涂涂層和激光表面改性區(qū)都存在有非平衡T'' 四方相,但是經(jīng)過激光表面改性后,噴涂涂層中的單斜相M消失,同時在2θ為72-76°范圍內非平衡T'' 在[004]方向增強。拉伸結果顯示,樁釘結構選擇性激光表面改性涂層的結合強度由噴涂涂層的7.3MPa增加到13.3MPa。隔熱測試結果表明,相對于噴涂涂層,樁釘結構激光表面改性涂層的隔熱性能有所下降,這是由于激光表面改性造成陶瓷層結構改變所致。

    Abstract:

    In this paper, yttria partially stabilized zirconia (YSZ) thermal barrier coatings (TBCs) were deposited by air plasma spraying (APS) method on nickle-based superalloy with initially sprayed NiCoCrAlYTa bond coat. After that, the surface of the plasma sprayed TBCs was subjected to the peg-nail structure selective laser modification using a Nd:YAG pulsed laser. The microstructure and performance of the plasma sprayed and laser modified YSZ coatings were investigated. The results revealed that the peg-nail structure selective laser modification helped to reduce the surface roughness considerably, eliminate to surface porosities and produced a network of continuous cracks perpendicular to the surface. The microstructure of laser modified area consisted of columnar grains in the cross-section and equiaxed grains on the surface. XRD patterns showed that both as-sprayed and the peg-nail structure laser modified coatings consisted of nonequibrium tetragonal (T'') phase, however, monoclinic (M) phase disappeared and intensity of T'' phase slightly increased in the range of 72-76°(2θ) after the peg-nail structure laser modification. It has been found that the average bond strength YSZ coatings was enhanced from 7.3 MPa to 13.3 MPa after the peg-nail structure laser modification. Thermal insulation capability of the peg-nail structure laser modified TBCs, as compared to the as-sprayed TBCs, was decreased due to microstructure change in the ceramic top coat.

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常發(fā),周克崧.等離子噴涂YSZ熱障涂層樁釘結構激光表面改性[J].稀有金屬材料與工程,2017,46(3):577~584.[changfa, zhou ke song. The peg-nail structure selective laser modification of plasma sprayed YSZ thermal barrier coatings[J]. Rare Metal Materials and Engineering,2017,46(3):577~584.]
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  • 收稿日期:2014-11-18
  • 最后修改日期:2015-05-28
  • 錄用日期:2015-07-10
  • 在線發(fā)布日期: 2017-05-18
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