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Y含量對Zr47–xCu46Al7Yx合金非晶形成能力及力學(xué)性能的影響
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西南林業(yè)大學(xué)

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TG166/TG139.8

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國家自然科學(xué)基金項目(面上項目,重點項目,重大項目)


Effect of Yttrium Content on the Glass-forming Ability and Mechanical Properties of Zr47–xCu46Al7Yx Bulk Metallic Glasses
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Southwest Forestry University

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    摘要:

    采用高真空電弧熔煉噴射成形法制備Zr47–xCu46Al7Yx(x=3~8)大塊非晶合金。采用X射線衍射分析、差示掃描量熱儀、掃描電子顯微鏡、壓縮試驗和硬度試驗分別研究Y含量對合金的非晶形成能力、顯微組織、斷口形貌及力學(xué)性能的影響。研究結(jié)果表明:Y含量對合金系的非晶形成能力和力學(xué)性能有顯著影響,(4~7)at%Y含量試樣由完全非晶組織構(gòu)成,其過冷液相區(qū)ΔTx為56~71K,約化玻璃轉(zhuǎn)變溫度Trg為0.665~0.678,但在3與8at%Y含量試樣非晶基體中出現(xiàn)了極少量結(jié)晶組織。大塊非晶具有較好力學(xué)性能,其抗壓強(qiáng)度為1803~1899MPa,維氏硬度為5.22~5.39GPa,且具有較強(qiáng)非晶形成能力的試樣相應(yīng)地具有較好的力學(xué)性能。大塊非晶在壓縮中以純彈性變形方式發(fā)生脆性斷裂,斷口光滑平整,為典型脈絡(luò)狀花紋。

    Abstract:

    Zr47–xCu46Al7Yx(x=3~8) bulk metallic glasses (BMGs) were prepared by injection in copper mould with arc melting. The effect of Y content on the glass-forming ability (GFA), microstructures, fractured surfaces and mechanical properties of the alloys were investigated by using X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscope (SEM), compression tests and hardness tests, respectively. Results show: Y content has evident effect on the GFA and mechanical properties, the BMGs with 4~7at%Y contents only contain amorphous phases and possess a larger supercooled liquid region ΔTx with value of 56~71K and a better reduced glass transition temperature Trg with value of 0.665~0.678, but very few crystalline phases appear on the BMGs with 3 and 8at%Y contents. The BMGs possess better mechanical properties with compression strength of 1803-1899MPa and Vickers hardness of 5.22~5.39GPa, the BMGs with the better GFA correspondingly possess the better mechanical properties. In compression test, the BMGs happen brittle fracture by pure elastic deformation way, and all fractured surfaced are flat and smooth with typical vein-like morphologies.

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王遠(yuǎn). Y含量對Zr47–xCu46Al7Yx合金非晶形成能力及力學(xué)性能的影響[J].稀有金屬材料與工程,2017,46(2):427~432.[Wang Yuan. Effect of Yttrium Content on the Glass-forming Ability and Mechanical Properties of Zr47–xCu46Al7Yx Bulk Metallic Glasses[J]. Rare Metal Materials and Engineering,2017,46(2):427~432.]
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  • 收稿日期:2014-11-05
  • 最后修改日期:2014-11-29
  • 錄用日期:2014-12-26
  • 在線發(fā)布日期: 2017-04-10
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