Si基襯底上分別制備了BiFeO3(BFO)和Sr1-xLaxFe12-xCoxO19(x=0~0.3)的單層及2-2型BiFeO3/Sr1-xLaxFe12-xCoxO19疊層式復(fù)合結(jié)構(gòu)薄膜。采用X射線(xiàn)衍射(XRD)、掃描電子顯微鏡(SEM)和材料綜合物性測(cè)試系統(tǒng)(PPMS)對(duì)薄膜樣品的微觀(guān)結(jié)構(gòu)、表面形貌以及磁學(xué)性能進(jìn)行了測(cè)試分析。結(jié)果表明,隨著x的增加,Sr1-xLaxFe12-xCoxO19單層膜的矯頑力先少量減小后增加,剩磁比起初不變?nèi)缓筮f增,而剩余磁化強(qiáng)度一直減小。當(dāng)x=0.3時(shí),其矯頑力和剩磁比均達(dá)到最大值,分別為6165Oe和0.69,而剩余磁化強(qiáng)度達(dá)到最小值為50emu/cm3;復(fù)合薄膜的矯頑力及剩磁比先增加后減小,剩余磁化強(qiáng)度一直減小,在x=0.2矯頑力和剩磁比均達(dá)到最大值,分別為5333Oe和0.73,當(dāng)x=0.3時(shí)矯頑力和剩磁比明顯減弱,分別為2151Oe和0.4,此時(shí)剩余磁化強(qiáng)度為最小值19emu/cm3。"/>

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磁控濺射制備BiFeO3/Sr1-xLaxFe12-xCoxO19復(fù)合薄膜及其磁性能研究
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桂林電子科技大學(xué),桂林電子科技大學(xué),桂林電子科技大學(xué)

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中圖分類(lèi)號(hào):

TB43;O484

基金項(xiàng)目:

廣西自然科學(xué)基金項(xiàng)目(2012GXNSFAA053198)、國(guó)家自然科學(xué)基金項(xiàng)目(51161005)


The Preparation and Magnetic Properties of BiFeO3/Sr1-xLaxFe12-xCoxO19 Composite Films by Magnetron Sputtering
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Guilin University of Electronic Technology,Guilin University of Electronic Technology,Guilin University of Electronic Technology

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    摘要:

    摘 要: 室溫下采用射頻磁控濺射法,在P型<100>Si基襯底上分別制備了BiFeO3(BFO)和Sr1-xLaxFe12-xCoxO19(x=0~0.3)的單層及2-2型BiFeO3/Sr1-xLaxFe12-xCoxO19疊層式復(fù)合結(jié)構(gòu)薄膜。采用X射線(xiàn)衍射(XRD)、掃描電子顯微鏡(SEM)和材料綜合物性測(cè)試系統(tǒng)(PPMS)對(duì)薄膜樣品的微觀(guān)結(jié)構(gòu)、表面形貌以及磁學(xué)性能進(jìn)行了測(cè)試分析。結(jié)果表明,隨著x的增加,Sr1-xLaxFe12-xCoxO19單層膜的矯頑力先少量減小后增加,剩磁比起初不變?nèi)缓筮f增,而剩余磁化強(qiáng)度一直減小。當(dāng)x=0.3時(shí),其矯頑力和剩磁比均達(dá)到最大值,分別為6165Oe和0.69,而剩余磁化強(qiáng)度達(dá)到最小值為50emu/cm3;復(fù)合薄膜的矯頑力及剩磁比先增加后減小,剩余磁化強(qiáng)度一直減小,在x=0.2矯頑力和剩磁比均達(dá)到最大值,分別為5333Oe和0.73,當(dāng)x=0.3時(shí)矯頑力和剩磁比明顯減弱,分別為2151Oe和0.4,此時(shí)剩余磁化強(qiáng)度為最小值19emu/cm3。

    Abstract:

    Abstract: BiFeO3(BFO) and Sr1-xLaxFe12-xCoxO19(x=0~0.3)monolayer films and 2-2 BiFeO3 / Sr1-xLaxFe12-xCoxO19 stacked composite films were prepared on the P-type <100> Si-based substrates by magnetron sputtering at room temperature. The microstructure, surface morphology and magnetic properties of thin film samples were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and material properties of a comprehensive test system (PPMS).The results indicate that with the increase of x, the coercive force of Sr1-xLaxFe12-xCoxO19 monolayer first increase after small decreases, residual magnetism ratio unchanged at first and then increase, while the residual magnetization have been reduced. When the x = 0.3 the coercive force and the residual magnetism ratio reached a maximum value of 6165Oe and 0.69, and the residual magnetization reaches the minimum value of 50emu/cm3; The coercive force and residual magnetism ratio of the composite film decreases after the first increases, while the residual magnetization have been reduced. At x = 0.2 the coercive force and residual magnetism ratio reached a maximum value of 5333Oe and 0.73. When the x = 0.3 when the ratio of the coercive force and the residual magnetism ratio decreased significantly as 2151Oe and 0.4, the residual magnetization in this case is the minimum value of 19 emu/cm3.

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顧正飛,李振昕,江民紅.磁控濺射制備BiFeO3/Sr1-xLaxFe12-xCoxO19復(fù)合薄膜及其磁性能研究[J].稀有金屬材料與工程,2017,46(2):415~420.[GuZhengFei, LiZhenXin, JiangMinHong. The Preparation and Magnetic Properties of BiFeO3/Sr1-xLaxFe12-xCoxO19 Composite Films by Magnetron Sputtering[J]. Rare Metal Materials and Engineering,2017,46(2):415~420.]
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  • 收稿日期:2014-10-31
  • 最后修改日期:2014-12-12
  • 錄用日期:2015-01-13
  • 在線(xiàn)發(fā)布日期: 2017-04-10
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