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以Ti(OBu)4為鈦源、三聚氰胺為氮源通過(guò)溶膠-凝膠法制備高活性光催化劑TiO2/g-C3N4
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江蘇理工學(xué)院 化學(xué)化工學(xué)院

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國(guó)家自然科學(xué)基金項(xiàng)目(面上項(xiàng)目,重點(diǎn)項(xiàng)目,重大項(xiàng)目)


Preparation of a high activity TiO2/g-C3N4 photocatalyst via a facile sol-gel method taking Ti(OBu)4 as Ti source and melamin
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School of Chemistry and Chemical Engineering, Jiangsu University of Technology

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    摘要:

    以Ti(OBu)4為鈦源、三聚氰胺為氮源,通過(guò)溶膠-凝膠和高溫煅燒兩步法制備了高活性可見(jiàn)光光催化劑TiO2/g-C3N4。利用X射線(xiàn)粉末衍射(XRD)、透射電子顯微鏡(TEM)和紫外-可見(jiàn)漫反射光譜(UV-vis diffuse reflectance spectra )等手段對(duì)其進(jìn)行了表征。結(jié)果表明:TiO2鑲嵌在石墨相的g-C3N4中,并與g-C3N4構(gòu)成TiO2/g-C3N4復(fù)合材料。由于TiO2與g-C3N4的協(xié)同作用,擴(kuò)大了TiO2/g-C3N4的可見(jiàn)光吸收范圍和強(qiáng)度,因而其具有很好的可見(jiàn)光光催化性能。

    Abstract:

    A highly active photocatalyst TiO2/g-C3N4 was facilely synthesized by a facile two-step method, sol-gel method and calcination using Ti(OBu)4 as Ti source and melamine as nitrogen source. The structural and morphological properties of the resultant photocatalysts were characterized. The results showed that TiO2/g-C3N4 was formed and TiO2 was beset with graphite-like carbon nitride of layer structure. TiO2/g-C3N4 exhibited obviously enhanced visible light photocatalytic activity, and the degradation efficiency of Methylene blue (MB) reached 94.46% after irradiation for 1h, which was much higher than that of g-C3N4 and TiO2. The improved photocatalytic activity of TiO2/g-C3N4 was attributable to its wide spectrum responsive range, strong visible light adsorption capability, and the synergistic effect between TiO2 and g-C3N4. The mechanism of photocatalytic reaction was discussed.

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張春勇.以Ti(OBu)4為鈦源、三聚氰胺為氮源通過(guò)溶膠-凝膠法制備高活性光催化劑TiO2/g-C3N4[J].稀有金屬材料與工程,2017,46(2):322~325.[Zhang Chunyong. Preparation of a high activity TiO2/g-C3N4 photocatalyst via a facile sol-gel method taking Ti(OBu)4 as Ti source and melamin[J]. Rare Metal Materials and Engineering,2017,46(2):322~325.]
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  • 收稿日期:2014-10-26
  • 最后修改日期:2016-03-27
  • 錄用日期:2016-04-26
  • 在線(xiàn)發(fā)布日期: 2017-04-10
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