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大變形純鈦微弧氧化膜層的生物摩擦學(xué)性能研究
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江蘇大學(xué)機(jī)械工程學(xué)院,常州大學(xué)

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TH117

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Bio-tribological Properties of Micro-arc Oxidation Coating on Large Plastic Deformed Titanium
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School of Mechanical Engineering, Jiangsu University,Changzhou University

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    摘要:

    采用微弧氧化法在純鈦及大變形純鈦表面制備多孔氧化膜層,研究微弧氧化膜層在干摩擦、模擬體液和小牛血清不同潤滑介質(zhì)條件下的生物摩擦學(xué)性能,探討鈦基材組織細(xì)化對(duì)其膜層表面摩擦磨損性能的影響。結(jié)果表明:與純鈦微弧氧化膜層相比,大變形純鈦微弧氧化膜層耐磨性能更優(yōu)的原因在于鈦基材晶粒的細(xì)化使得晶體缺陷增多,為微弧氧化膜層的形核提供了更多的能量,反應(yīng)生成的TiO2膜層硬度更強(qiáng),膜層表面更致密均勻光滑,提高了其摩擦磨損性能所致。大變形純鈦微弧氧化膜層在小牛血清潤滑時(shí)的摩擦系數(shù)和磨損程度都優(yōu)于干摩擦和模擬體液潤滑條件下的摩擦系數(shù)與磨損情況。這歸因于小牛血清于摩擦表面形成的化學(xué)反應(yīng)膜及物理吸附膜,起到了更有效的潤滑、冷卻與承載作用。

    Abstract:

    This paper reports the use of micro-arc oxidation(MAO) to prepare porous oxide coatings on the surface of titanium and large plastic deformed titanium. The bio-tribological properties of the MAO coatings were evaluated under different lubrication medium conditions, namely dry friction, stimulated body liquid, and calf serum. The effect of structure refinement of the titanium substrate on the friction wear properties of the coating surface was also investigated. The MAO coating obtained from large plastic deformed titanium exhibits higher abrasion resistance than the MAO coating on titanium because of improved friction wear properties. To be more specific, the structure refinement of the titanium substrate results in more crystal defects and provides more energy for nucleation on the MAO coating,which makes the TiO2 coating formed through the reaction harder, the coating surface more compact, uniform, and smooth.The friction coefficient and degree of wear of the MAO coating formed from large plastic deformed titanium under calf serum lubrication are better than those under dry friction and stimulated body liquid. This finding could be attributed to more effective lubrication and cooling, as well as to the roles of the coatings formed on the friction surface through chemical reaction and physical adsorption under calf serum lubrication.

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徐琳,丁建寧.大變形純鈦微弧氧化膜層的生物摩擦學(xué)性能研究[J].稀有金屬材料與工程,2017,46(1):127~134.[Xu Lin, Ding Jianning. Bio-tribological Properties of Micro-arc Oxidation Coating on Large Plastic Deformed Titanium[J]. Rare Metal Materials and Engineering,2017,46(1):127~134.]
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  • 收稿日期:2014-10-17
  • 最后修改日期:2014-11-07
  • 錄用日期:2015-03-25
  • 在線發(fā)布日期: 2017-03-16
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