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Zr-4合金癤狀腐蝕與晶粒取向的關系
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上海大學材料研究所

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國家自然科學基金項目(面上項目,重點項目,重大項目)


The Relationship between Nodular Corrosion Resistance and Grain Orientation of Zircaloy-4
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Institute of materials, Shanghai University

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    摘要:

    Zr-4大晶粒樣品在高壓釜中經(jīng)過500 ℃/10.3 MPa過熱蒸汽腐蝕,研究了不同晶粒表面上氧化膜厚度與晶粒取向的關系。結果表明:樣品腐蝕時氧化膜的生長表現(xiàn)出明顯的各向異性特征,晶粒表面取向在(10-10)和(11-20)之間時,氧化膜生長速率最快,腐蝕3 h后最先出現(xiàn)癤狀腐蝕斑,當腐蝕時間延長至30 h時,晶粒表面的極點在反極圖中間位置的那些晶粒表面上也逐漸產(chǎn)生癤狀腐蝕斑,而晶粒表面取向在(0001)晶面附近時氧化膜生長速率最慢,即使腐蝕30 h也沒有產(chǎn)生癤狀腐蝕斑。實驗結果表明了當?shù)诙啻笮『头植家约癋e,Cr合金元素在α-Zr中的固溶含量相同的情況下,Zr-4合金的耐癤狀腐蝕性能與樣品表面的晶粒取向有著密切的關系。

    Abstract:

    The relationship between oxide thickness and grain orientations was investigated using Zircaloy-4 coarse-grained specimens corroded at 500 ℃/10.3 MPa in superheated steam. The results indicate that the growth of the oxide films formed on Zircaloy-4 specimens shows remarkably anisotropic characteristics. The growth rate of the oxide films formed on the grain surfaces with the orientation between prismatic plane of (10-10) and (11-20) was fastest, and the nodular corrosion spots were formed earlier after 3 h exposure. The grain surfaces with the orientation whose poles were located at the middle of inverse pole figure started to form the nodular corrosion spots for 30 h exposure gradually. The thinnest oxide layers were detected on the grain surfaces with the orientation nearby basal plane (0001), and the nodular corrosion spots did not appeared after 30 h exposure. The experimental results show that the nodoular corrosion resistance of Zircaloy-4 is closely related to the grain orientations when the distribution and the size of second phase particles, and the solid solution content of Fe and Cr alloying elements in α-Zr matrix are at the same level.

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陳傳明. Zr-4合金癤狀腐蝕與晶粒取向的關系[J].稀有金屬材料與工程,2016,45(12):3213~3217.[Chen Chuanming. The Relationship between Nodular Corrosion Resistance and Grain Orientation of Zircaloy-4[J]. Rare Metal Materials and Engineering,2016,45(12):3213~3217.]
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  • 收稿日期:2014-09-15
  • 最后修改日期:2014-10-11
  • 錄用日期:2014-11-21
  • 在線發(fā)布日期: 2017-02-06
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