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Gold Leaf Corrosion in Moisture Acid Atmosphere at Ambient Temperature
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Gold Leaf Corrosion in Moisture Acid Atmosphere at Ambient Temperature
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    摘要:

    近年來許多貼金文物損壞嚴(yán)重。將金箔暴露于潮濕的SO2、NO2及其混合模擬氣氛中以研究其在室溫環(huán)境氣氛中腐蝕的可能性。與金在室溫下僅在王水中腐蝕的常識不同,金箔在這3種氣體里都發(fā)生了腐蝕。在潮濕的SO2氣氛中,金箔腐蝕的主要原因是雜質(zhì)銅的優(yōu)先氧化。在潮濕的NO2氣氛和SO2與NO2的混合氣氛中,金箔腐蝕的主要原因是雜質(zhì)的優(yōu)先氧化結(jié)合金本身的氧化。其中金的氧化是由于其加工過程中大的冷加工變形導(dǎo)致的高缺陷密度。金在室溫下酸性氣氛中腐蝕現(xiàn)象的發(fā)現(xiàn)不僅擴展了對金的性能的理解,還對貼金文物和藝術(shù)品的保護提供了有益的指導(dǎo)

    Abstract:

    Many cultural relics adhered with gold leaf (e.g. gold foil) are found damaged seriously in recent years. In this paper, gold leaf was exposed in the imitating atmosphere of moisture SO2, NO2 and their mixture to investigate its corrosion possibility in environment atmosphere at ambient temperature. Following phenomena were observed. The gold leaf was corroded in all these three atmospheres, which is contrary to the common sense that gold can only be corroded in aqua regia at ambient temperature. In SO2 atmosphere, the main reason of the corrosion is the preferential oxidation of the impurity of Cu. In the atmospheres of NO2 and the mixture of SO2 and NO2, the main reason of the corrosion is the combination of the preferential oxidation of the impurity and the oxidation of gold itself caused by the high defect density stemmed from the severe cold deformation during its processing. The discovery that gold can be corroded in moisture acid atmosphere at ambient temperature expands the understanding of the character of gold, and provides beneficial guidance to the protection of culture relics and modern artworks decorated with gold foil

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田興玲,馬清林,鄭茗天,李志林. Gold Leaf Corrosion in Moisture Acid Atmosphere at Ambient Temperature[J].稀有金屬材料與工程,2014,43(11):2637~2642.[Tian Xingling, Ma Qinglin, Zheng Mingtian, Li Zhilin. Gold Leaf Corrosion in Moisture Acid Atmosphere at Ambient Temperature[J]. Rare Metal Materials and Engineering,2014,43(11):2637~2642.]
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  • 收稿日期:2013-12-18
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  • 在線發(fā)布日期: 2015-04-07
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