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SmCo1-xFexAsO的多重磁性轉(zhuǎn)變
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國家磁約束核聚變能研究專項(xiàng)(2011GB112001);國際合作項(xiàng)目(2013DFA51050);國家自然科學(xué)基金(11104224,11004162,51271155);高等學(xué)校博士學(xué)科點(diǎn)專項(xiàng)科研基金新教師類課題(20110184120029);四川省科技計(jì)劃項(xiàng)目(2011JY0031,2011JY0130);中央高?;究蒲袠I(yè)務(wù)費(fèi)專項(xiàng)資金(SWJTU11BR063)


Multiple Magnetic Transitions in SmCo1-xFexAsO
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    摘要:

    采用固相反應(yīng)法,制備出一系列 SmCo1-xFexAsO(x = 0,0.05,0.1,0.2)多晶樣品。XRD測(cè)試結(jié)果表明所有樣品均為單相,且具有ZrCuSiAs型四方結(jié)構(gòu),隨著摻雜量的增加,晶格參數(shù)a逐漸減小,c逐漸增加。磁性測(cè)量結(jié)果表明,低摻雜量樣品在5 ~ 300 K之間先后經(jīng)歷了反鐵磁-鐵磁-順磁的磁性轉(zhuǎn)變,低場(chǎng)下的M - T曲線表現(xiàn)出明顯的不可逆性,且隨著摻雜量的增加,反鐵磁轉(zhuǎn)變溫度降低,鐵磁轉(zhuǎn)變溫度向高溫方向移動(dòng),表明樣品的反鐵磁性逐漸被抑制,而鐵磁性逐漸增強(qiáng)。M - H曲線表明,在反鐵磁轉(zhuǎn)變溫度以下,摻雜量x < 0.2的樣品,隨著磁場(chǎng)的增加發(fā)生了由反鐵磁到鐵磁性的變磁性轉(zhuǎn)變,且隨著摻雜量的增加,在同一溫度下的轉(zhuǎn)變磁場(chǎng)變小。在摻雜量x = 0.2時(shí),當(dāng)溫度降低到5 K時(shí)仍沒有觀察到變磁性轉(zhuǎn)變,在摻雜量x = 0.2附近可能存在變磁性臨界終點(diǎn)。

    Abstract:

    A series of polycrystalline sample SmCo1-xFexAsO (x=0, 0.05, 0.1, 0.2) was prepared by a solid-state reaction method. X-ray diffraction patterns indicate that all the samples have formed the ZrCuSiAs-type structure. The decrease of the lattice constant a and the increase of c are observed with the increased doping amount. Magnetic measurement results show that complicated magnetism consists of antiferromagnetic, ferromagnetic and paramagnetic between 5 and 300 K. Strong irreversibility in M-T curve is observed just below the Curie temperature. With Fe content increasing, antiferromagnetic order of SmCoAsO is suppressed, and its ferromagnetism is enhanced. M-H curves show that metamagnetic transition occurs below their antiferromagnetic transition temperature for samples with x<0.2, and the transition field decreases with increasing Fe content. When Fe content reaches to 0.2, no metamagnetic transition can be observed down to 5 K. All of the results are consistent with the existence of a metamagnetic critical end point at critical concentration which is close to 0.2.

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蘇春燕,陳永亮,周大進(jìn),王小峰,李平原,崔雅靜,趙 勇. SmCo1-xFexAsO的多重磁性轉(zhuǎn)變[J].稀有金屬材料與工程,2014,43(10):2431~2434.[Su Chunyan, Chen Yongliang, Zhou Dajin, Wang Xiaofeng, Li Pingyuan, Cui Yajing, Zhao Yong. Multiple Magnetic Transitions in SmCo1-xFexAsO[J]. Rare Metal Materials and Engineering,2014,43(10):2431~2434.]
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  • 收稿日期:2013-10-25
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  • 在線發(fā)布日期: 2015-04-07
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