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Isothermal Beta Grain Growth Kinetics of TC4-DT Titanium Alloy under Two Different Prior Processing Conditions: Deformed vs. Undeformed
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Isothermal Beta Grain Growth Kinetics of TC4-DT Titanium Alloy under Two Different Prior Processing Conditions: Deformed vs. Undeformed
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National Natural Science Foundation of China (51101119)

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    摘要:

    研究了具有初始等軸組織的TC4-DT鈦合金在變形和未變形的狀態(tài)下在β單相區(qū)等溫加熱時的晶粒長大動力學。變形在兩相區(qū)進行,變形程度為60%,變形后空冷。加熱溫度分別選取相變點以上10、20、30 ℃, 保溫時分別為2、5、10、30、60、120 min。利用金相分析軟件對晶粒尺寸進行了定量測定并分析獲得了兩種條件下的晶粒生長的時間指數(shù)和激活能。未變形試樣的晶粒生長的時間指數(shù)和激活的變化范圍分別是0.34~0.35和86.8~130 kJ·mol-1, 在變形條件下變?yōu)?.36~0.39和76.6~110 kJ·mol-1。研究結果表明在相同的加熱條件下,變形試樣具有較高的晶粒生長指數(shù)和較低的生長激活能。這是因為晶粒生長時間指數(shù)隨溫度的變化和生長激活能隨時間的變化與固溶原子的擴散和晶界的遷移的交互作用有關,而變形可以促進原子的擴散和晶界的遷移。另外還研究了在不同的加熱溫度、時間以及變形條件下晶粒尺寸的均勻度的變化情況,這種變化是β相的形核速率和生長速率在上述因素的影響下共同作用的結果。

    Abstract:

    β grain growth kinetics of TC4-DT titanium alloy under two different prior processing conditions (deformed vs. undeformed) was investigated during isothermal heat treatments. Deformation was carried out in α+β two-phase field with deformation degree of 60% and air cooling. Heat treatment scheme with the temperatures above β transus temperature 10, 20, 30 °C and soaking time of 2, 5, 10, 30, 60, 120 min was used. The grain size parameters have been obtained by means of the image analysis software. Growth time exponent (n) and activation energy (Q) have been established for both conditions. For the undeformed samples, n varied in the range of 0.34~0.35 and Q in the range of 86.8~130 kJ·mol-1, while after deformation, the values of n and Q changed in the domain of 0.36~0.39 and 76.6~110 kJ·mol-1, respectively. Results show that the samples subjected to deformation exhibit higher growth time exponent and lower activation energy compared to the samples without deformation under the same heat treatment conditions. The variations of the growth time exponent with temperature and the activation energy with soaking time are ascribed to the interaction between diffusion of solute atoms and migration of grain boundaries both of which can be promoted by deformation. The influences of heating temperature, time and deformation on the uniformity of grain size were also studied and the intrinsic mechanism is attributed to the combined effect of β phase nucleation rate and β phase growth velocity under the above factors.

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彭小娜,郭鴻鎮(zhèn),秦 春,石志峰,趙張龍. Isothermal Beta Grain Growth Kinetics of TC4-DT Titanium Alloy under Two Different Prior Processing Conditions: Deformed vs. Undeformed[J].稀有金屬材料與工程,2014,43(8):1855~1861.[Peng Xiaona, Guo Hongzhen, Qin Chun, Shi Zhifeng, Zhao Zhanglong. Isothermal Beta Grain Growth Kinetics of TC4-DT Titanium Alloy under Two Different Prior Processing Conditions: Deformed vs. Undeformed[J]. Rare Metal Materials and Engineering,2014,43(8):1855~1861.]
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  • 收稿日期:2013-10-29
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  • 在線發(fā)布日期: 2015-01-04
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