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鎂合金與不銹鋼的瞬間液相擴(kuò)散連接
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西安科技大學(xué)

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TG457

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Transient Liquid Phase Bonding of Magnesium Alloy AZ31B and 304 Stainless Steel
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Xi’an University of Science and Technology

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National Natural Science Foundation of China (50901062, 51271152)

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    摘要:

    以Cu為中間夾層對AZ31B鎂合金與304不銹鋼進(jìn)行瞬間液相擴(kuò)散連接,研究了焊接接頭的微觀結(jié)構(gòu)和連接強(qiáng)度。結(jié)果表明,510℃×30min、530℃×10min時(shí),接頭界面區(qū)沒有出現(xiàn)共晶液相,界面結(jié)合較弱;520℃×30min、530℃×20min時(shí),接頭界面區(qū)形成Mg-Cu共晶液相,焊縫寬度顯著增加,界面結(jié)合強(qiáng)度提高;530℃×30min,鎂基體向共晶液相溶解,鎂基體一側(cè)形成350μm的層狀擴(kuò)散區(qū),接頭界面依靠共晶液相在不銹鋼基體表面的潤濕鋪展形成冶金結(jié)合,接頭顯微組織依次是Mg-Cu共晶組織層、富Mg固溶體層、彌散分布于鎂合金基體的Mg17(Cu,Al)12相和分布于鎂合金晶界的Mg-Cu-Al三元化合物所組成的鎂合金基體滲透區(qū),其剪切強(qiáng)度達(dá)到最大(52MPa);540℃×30min、530℃×40min時(shí),界面擴(kuò)散區(qū)的共晶液相發(fā)生等溫凝固,鎂合金基體晶界處Mg-Cu-Al三元金屬間化合物呈連續(xù)網(wǎng)狀分布,接頭的剪切強(qiáng)度降低。AZ31B基體發(fā)生了再結(jié)晶及晶粒長大,530℃×30min產(chǎn)生退火孿晶,540℃×30min時(shí)晶粒內(nèi)析出第二相并顯著長大,基體出現(xiàn)了不同程度的軟化現(xiàn)象

    Abstract:

    Transient liquid-phase bonding of magnesium alloy (AZ31B) to stainless steel (304) was performed using a copper interlayer. The microstructure and bonding strength of the bonded joint were studied. The results show that when the welding condition is 510℃×30min or 530℃×10min, no eutectic phase was observed in the welded joint and the metallurgical bond is weak. When the welding condition is 520℃×30min or 530℃×20min, the joint interface produces Mg-Cu eutectic. A significant increasing occurs in weld width and interfacial bonding strength increases too. At 530℃×30min, the magnesium matrix dissolves into the eutectic liquid , and the laminar diffusion region with a width of about 350μm forms in the welded joint at the magnesium side, besides,the interface forms a metallurgical bond relying on the Mg-Cu eutectic liquid wetting and spreading to the stainless steel surface. Microstructure followed by Mg-Cu eutectic layer, Mg-rich solid solution layer , Mg17(Cu,Al)12 dispersed in magnesium alloy matrix and permeability zones of Mg-Cu-Al ternary compounds distributed in grain boundaries of magnesium alloy. The shear strength of the joint reaches the highest value of (52MPa). With the welding condition of 540℃×30min or 530℃×40min, eutectic liquid on interfacial diffusion zone occurs isothermal solidification and the joint shear strength decreases, which attributed to continuous network distributed of Mg-Cu-Al compound along the magnesium grain boundary. Recrystallization and grain growth happens to AZ31B matrix, and twins produced at 530℃×30min. The second phase precipitates within the grains and significantly grows at 540℃×30min. AZ31B matrix appears different degrees of softening phenomenon.

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引用本文

杜雙明.鎂合金與不銹鋼的瞬間液相擴(kuò)散連接[J].稀有金屬材料與工程,2016,45(8):2064~2070.[Du Shuangming. Transient Liquid Phase Bonding of Magnesium Alloy AZ31B and 304 Stainless Steel[J]. Rare Metal Materials and Engineering,2016,45(8):2064~2070.]
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  • 收稿日期:2014-07-09
  • 最后修改日期:2014-11-15
  • 錄用日期:2015-02-06
  • 在線發(fā)布日期: 2016-10-09
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