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微量Y和Hf對高鈮TiAl基合金高溫抗氧化性的影響
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國家自然科學(xué)基金 (50801047)


Influence of Trace Y and Hf on the High-Temperature Oxidation Resistance of TiAl Based Alloys with High Nb Content
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    摘要:

    使用元素Hf和Y對Ti-45Al-8Nb合金進行了微合金化,研究了微合金化前后高鈮TiAl基合金在900 ℃靜止空氣中的斷續(xù)氧化行為。結(jié)果表明,與Ti-45Al-8Nb合金相比,0.5Hf (mol%)微合金化后合金的抗氧化性無明顯變化,0.1Y (mol%)微合金化后合金抗氧化性增強,0.5Hf與0.1Y聯(lián)合微合金化后合金氧化膜與基體粘附性明顯增強,但合金氧化增重明顯。對氧化膜進行的掃描電鏡(SEM)、能譜分析(EDS)及X射線衍射(XRD)分析表明,單獨添加Y及Hf、Y聯(lián)合添加促進了合金中形成以Al2O3為主的連續(xù)致密的氧化層,Hf、Y聯(lián)合微合金化的合金中存在局部內(nèi)氧化現(xiàn)象降低了該合金的抗氧化性

    Abstract:

    The interrupted oxidation behavior of Hf and Y micro-alloyed TiAl-based alloys with high Nb content at 900 oC in static air was investigated. The results show that the addition of 0.5%Hf (mol%, similarly hereinafter) has few effects on the oxidation resistance of the high-Nb alloy, the addition of 0.1%Y improves the oxidation resistance, while the combined addition of 0.1%Y and 0.5% Hf enhances the adherence of oxide scale but reduces the oxidation resistance. Oxidized samples were examined by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and X-ray diffraction analysis (XRD). It is found that the addition of 0.1%Y and the combined addition of 0.5%Hf and 0.1%Y promote the formation of continuous and compact Al2O3 oxide scale. The combined addition of 0.5%Hf and 0.1%Y into the high-Nb alloy results in the partial internal oxidation of the alloy, impairing the oxidation resistance of TiAl

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王艷晶,宋玫錦,王繼杰,杜興蒿.微量Y和Hf對高鈮TiAl基合金高溫抗氧化性的影響[J].稀有金屬材料與工程,2014,43(7):1697~1701.[Wang Yanjing, Song Meijin, Wang Jijie, Du Xinghao. Influence of Trace Y and Hf on the High-Temperature Oxidation Resistance of TiAl Based Alloys with High Nb Content[J]. Rare Metal Materials and Engineering,2014,43(7):1697~1701.]
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  • 收稿日期:2013-07-05
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  • 在線發(fā)布日期: 2014-12-15
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