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載銀磁性Fe3O4納米粒子的制備與催化及抗菌性能的研究
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西南民族大學(xué)

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國家自然科學(xué)基金


Study on Preparation, Catalytic and Antibacterial Properties of Silver-deposited Fe3O4 Nanoparticles
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Southwest University for Nationalities

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    摘要:

    利用磁性納米粒子Fe3O4表面的聚多巴胺 (PDA) 對銀離子的吸附作用,采用種子誘導(dǎo)法制備了載銀磁性納米粒子 (PDA-Fe3O4@Ag)。采用UV-Vis (紫外-可見) 光譜對PDA-Fe3O4@Ag納米粒子的制備過程進(jìn)行了分析,采用FTIR (紅外光譜)、XRD (X射線衍射儀)、TEM (透射電鏡) 和VSM (振動樣品磁強(qiáng)計(jì)) 等手段對所得的PDA-Fe3O4@Ag粒子進(jìn)行表征;研究了PDA-Fe3O4@Ag對4-硝基苯酚還原反應(yīng)的催化作用,還測試了其抗菌性能。結(jié)果表明,納米金種子的存在是制備PDA-Fe3O4@Ag納米粒子的關(guān)鍵;在外加磁場作用下該磁性催化劑可以容易地從反應(yīng)體系中分離,經(jīng)多次循環(huán)使用后仍具有良好的催化性能;此外PDA-Fe3O4@Ag納米粒子具有殺菌性能,且經(jīng)磁分離回收循環(huán)利用5次后仍呈現(xiàn)對金黃色葡萄球菌較好的殺菌效果。

    Abstract:

    Silver-deposited magnetic nanoparticles (PDA-Fe3O4@Ag) were prepared though the seed-mediated method exploiting the adsorption of silver ions by the polydopamine (PDA) which was coated on the surface of Fe3O4. The preparation process was studied using UV-Vis spectra and the prepared nanoparticles were characterized with several analytical techniques including Fourier-transform infrared (FT-IR), X-ray diffraction (XRD), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM). The catalytic action on the reduction of 4-nitrophenol and the antibacterial property of PDA-Fe3O4@Ag were studied. The result indicates that the existence of gold seeds is the key to prepare PDA-Fe3O4@Ag nanoparticles. The magnetic catalyst can be separated easily from the reaction system by applied magnetic field, and still has good catalytic performance after repeated recycling. In addition PDA-Fe3O4@Ag nanoparticles exhibit bactericidal properties, and still shows good bactericidal effect on S. aureus after recycling use for 5 times.

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左芳.載銀磁性Fe3O4納米粒子的制備與催化及抗菌性能的研究[J].稀有金屬材料與工程,2016,45(7):1887~1892.[Zuo Fang. Study on Preparation, Catalytic and Antibacterial Properties of Silver-deposited Fe3O4 Nanoparticles[J]. Rare Metal Materials and Engineering,2016,45(7):1887~1892.]
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  • 收稿日期:2014-06-19
  • 最后修改日期:2014-07-08
  • 錄用日期:2014-07-28
  • 在線發(fā)布日期: 2016-10-09
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