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堆內(nèi)構(gòu)件304L焊接件在除氧和氯離子環(huán)境中的應力腐蝕開裂研究
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中國原子能科學研究院

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TG

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國家重大專項資助項目2011ZX06004-009-0101,2011ZX06004-009-0402和核能開發(fā)資助項目HK?DG1001-20102301;國家科技攻關(guān)計劃


The stress corrosion cracking behavior of reactor components welded 304L stainless steel in deoxygenized and chloride ions so
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China Institute of Atomic Energy(CIAE)

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    摘要:

    采用高溫高壓慢應變速率拉伸試驗方法(SSRT),研究了在除氧環(huán)境下不同濃度氯離子對304L焊接件在模擬一回路高溫高壓硼鋰水介質(zhì)中氯致應力腐蝕開裂的影響。結(jié)果表明:當氯離子濃度為1mg/L時,其各項力學性能指標與惰性氮氣空白樣一致,表明在低濃度氯離子除氧條件下,304L焊接件沒有應力腐蝕敏感性。隨著氯離子含量(1mg/L-50mg/L)的增加,304L焊接件應力腐蝕敏感指數(shù)變化趨勢是增加。斷口側(cè)面沒有觀察到明顯的裂紋,氯離子濃度越低,斷口縮頸現(xiàn)象越明顯,表明主要是機械斷裂。氯離子濃度較高時,棱角部分出現(xiàn)微裂紋源,可能與棱角部分應力更為集中相關(guān)。所有樣品的斷裂位置都在焊縫和熱影響區(qū),在焊縫和熱影響區(qū)發(fā)生了巨大的形變,離斷口越近,變形越嚴重。焊接部位是304L堆內(nèi)構(gòu)件中薄弱環(huán)節(jié),應該成為應力腐蝕開裂和其他性能檢測的重點部位。

    Abstract:

    Stress corrosion cracking(SCC) of reactor components welded 304L stainless steel in deoxygenized solution with different concentration chloride ions was studied using slow strain rate testing (SSRT), the basic water chemistry is simulated in pressure water reactor(PWR) primary loop, high temperature and high pressure water containing boric and lithium ion. Results shown the mechanical properties of welded 304L in 1mg/L chloride solution is equal those of welded 304L in inert nitrogen atmosphere, which implied welded 304L is immune to SCC in deoxygenized solution with low concentration chloride. The tendency of SCC susceptibility of welded 304L increased with increasing chloride ion concentration at range of 1mg/L to 50mg/L. There is not obvious crack on the side of fracture, the lower the chloride concentration, the more obvious the necking-down phenomenon, which implied the fracture mechanics is mainly mechanical fracture. There appeared microcracks source at angular parts, which is relative the stress gathering at these parts. The fracture position all lay in the weld and heat affected zone. There occurred huge deformation in the weld and heat affected zone, the near the fracture, the serious the deformation. The welded parts are weaknesses in the reactor components, which should be key monitoring sites for SCC susceptibility and other properties.

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彭德全.堆內(nèi)構(gòu)件304L焊接件在除氧和氯離子環(huán)境中的應力腐蝕開裂研究[J].稀有金屬材料與工程,2016,45(7):1771~1776.[Peng DeQuan. The stress corrosion cracking behavior of reactor components welded 304L stainless steel in deoxygenized and chloride ions so[J]. Rare Metal Materials and Engineering,2016,45(7):1771~1776.]
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  • 收稿日期:2014-06-11
  • 最后修改日期:2014-06-19
  • 錄用日期:2014-07-01
  • 在線發(fā)布日期: 2016-10-09
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