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一種超超臨界電站用鎳鐵基高溫合金凝固和析出相的熱力學(xué)評(píng)估
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西安熱工研究院有限公司

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中圖分類(lèi)號(hào):

TG146.1

基金項(xiàng)目:

51301130,51301131


Thermodynamic calculations of solidification and phases precipitation behaviors of Ni-Fe based superalloys for ultra-supercr
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Xi’an Thermal Power Research Institute Com.,Ltd.

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    摘要:

    鎳鐵基高溫合金由于具有優(yōu)良的高溫強(qiáng)度、抗氧化/腐蝕能力以及良好的加工性和低價(jià)格,是制備700℃超超臨界電站關(guān)鍵高溫部件的候選合金。本文利用熱力學(xué)計(jì)算軟件JMatPro和鎳鐵基合金數(shù)據(jù)庫(kù),計(jì)算分析了一種新型γ′相強(qiáng)化鎳鐵基高溫合金的凝固特征溫度和熱力學(xué)平衡相的析出行為;評(píng)估了調(diào)整γ′相形成元素Al、Ti,抗蝕元素Cr和C含量對(duì)合金凝固特征溫度和相析出行為的影響。結(jié)果表明:合金主要相組成為γ、γ′、MC和M23C6;隨著Ti和Al含量的提高,γ′相的析出溫度和含量增加,Ti元素的影響更顯著;Cr含量的增加會(huì)降低合金液相線、固相線和M23C6相的析出溫度并致M23C6相的析出含量先增加后減小;增加C含量會(huì)減小合金的結(jié)晶溫度間隔、提高M(jìn)C和M23C6相的析出溫度和析出含量。本模擬研究結(jié)果將為合金的優(yōu)化設(shè)計(jì)提供參考。

    Abstract:

    Ni-Fe based superalloys are expected to be employed as 700℃ ultra-supercritical coal fired power plants because of its excellent high temperature strength, oxidation and corrosion resistance, low cost and high workability. In this paper, thermodynamic calculation software JMatPro and Ni-based database were used to analyze the solidification and equilibrium phase precipitation of a new Ni-Fe based superalloy. The effect of Al, Ti, Cr and C additions on the precipitation behaviors of strengthing phases was calculated. The results showed that the main constitution phases were γ、γ′、MC and M23C6. The precipitated temperature and amount of γ′ increased with the increasing Ti and Al contents. With the increase of Cr content, the solidus and liquidus temperature decreased and the amount of M23C6 increased firstly and then decreased. The additions of C content could reduce the freezing range and promote the amount and precipitated temperature of MC and M23C6. These results are beneficial to the superalloys design and development.

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趙新寶.一種超超臨界電站用鎳鐵基高溫合金凝固和析出相的熱力學(xué)評(píng)估[J].稀有金屬材料與工程,2016,45(6):1515~1520.[zhaoxinbao. Thermodynamic calculations of solidification and phases precipitation behaviors of Ni-Fe based superalloys for ultra-supercr[J]. Rare Metal Materials and Engineering,2016,45(6):1515~1520.]
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  • 收稿日期:2014-05-21
  • 最后修改日期:2014-07-29
  • 錄用日期:2014-09-28
  • 在線發(fā)布日期: 2016-10-08
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