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缺陷螢石型(Sm0.6Y0.4)2Zr2O7陶瓷中的短程有序化現(xiàn)象
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國家自然科學(xué)基金 (50972030);山東省自然科學(xué)基金 (ZR2012EMQ011)


Short-Range Order Phenomena in Defect Fluorite-Type (Sm0.6Y0.4)2Zr2O7 Ceramic
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    摘要:

    采用X射線衍射、高分辨透射電鏡、選區(qū)電子衍射以及拉曼光譜等技術(shù)手段研究了(Sm0.6Y0.4)2Zr2O7陶瓷的晶體結(jié)構(gòu)。X射線衍射表明,(Sm0.6Y0.4)2Zr2O7 陶瓷為單一立方相缺陷型螢石結(jié)構(gòu)。然而高分辨電鏡和選區(qū)電子衍射觀察結(jié)果顯示,在電子衍射花樣中除了缺陷型螢石相點陣的衍射外,還發(fā)現(xiàn)有對應(yīng)于燒綠石相的弱散射斑點。這表明在無序的缺陷型螢石相點陣中存在短程有序化現(xiàn)象。拉曼光譜結(jié)果進一步證實了在微米或納米尺度范圍內(nèi)存在短程有序化現(xiàn)象

    Abstract:

    The crystal structure of (Sm0.6Y0.4)2Zr2O7 ceramic has been investigated by X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM) coupled with selected area electron diffraction (SAED) and Raman spectroscopy. XRD result shows that (Sm0.6Y0.4)2Zr2O7 ceramic exhibits a single defect fluorite-type structure. However, HRTEM and SAED observation reveals that additional weak diffuse reflections belonging to the pyrochlore-type structure appear in the electron diffraction patterns expect for the characteristic reflections of the defect fluorite-type lattice, which suggests short-range ordering in the bulk defect fluorite lattice. Raman spectroscopy also confirms the short-range order phenomenon at the micro- or nano-scaled regions

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夏校良,鄭 軼,于硯廷,李 曄,歐陽家虎.缺陷螢石型(Sm0.6Y0.4)2Zr2O7陶瓷中的短程有序化現(xiàn)象[J].稀有金屬材料與工程,2014,43(5):1169~1172.[Xia Xiaoliang, Zheng Yi, Yu Yanting, Li Ye, Ouyang Jiahu. Short-Range Order Phenomena in Defect Fluorite-Type (Sm0.6Y0.4)2Zr2O7 Ceramic[J]. Rare Metal Materials and Engineering,2014,43(5):1169~1172.]
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  • 收稿日期:2013-05-07
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  • 在線發(fā)布日期: 2014-10-13
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