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稀土CeO2在6063Al表面Ni基激光熔覆中的作用機(jī)制
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桂林電子科技大學(xué)

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TG115

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國家自然科學(xué)基金項(xiàng)目(面上項(xiàng)目,重點(diǎn)項(xiàng)目,重大項(xiàng)目);


Mechanism of Rare Earth CeO2 on the Ni -Based Laser Cladding Layer of 6063 Al Surface
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GUILIN UNIVERSITY OF ELECTRONIC TECHNOLOGY

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    摘要:

    摘 要: 利用激光熔覆技術(shù),在6063Al表面制備了添加稀土CeO2的Ni60合金熔覆層,并通過金相顯微鏡、XRD、SEM和EDS等設(shè)備進(jìn)行測試分析,研究稀土CeO2對(duì)6063Al表面激光熔覆Ni基熔覆層組織、相結(jié)構(gòu)、成分等微觀結(jié)構(gòu)的影響,探討稀土氧化物CeO2的作用效果和機(jī)制。結(jié)果表明:加入5% CeO2可有效地減少Ni60熔覆層中的裂紋、孔洞,使熔覆層具有較好的組織形貌;5% CeO2 Ni60熔覆層和未加CeO2的Ni60熔覆層主要相結(jié)構(gòu)均為β-NiAl(Cr)和少量的NiAl3、Ni3Al、Al等,添加稀土后β-NiAl相的(110)、(200)、(211) 衍射峰和Al峰的強(qiáng)度有明顯降低,且有明顯的NiAl3相的峰;相比于未添加CeO2的Ni60熔覆層,添加CeO2后的熔覆層元素分布較為均勻,稀釋率降低;加入5% CeO2可使Ni60熔覆層的表層孔隙率大幅降低,細(xì)化作用明顯,晶粒分布較彌散,但對(duì)熔覆層底部微觀組織的改善作用不明顯。

    Abstract:

    Abstract: On the surface of 6063 aluminum alloys, using laser cladding technology prepared Ni60 alloy cladding layer with added rare earth CeO2, and by metallographic microscope, XRD, SEM and EDS equipment for the testing and analysis, researched the influence of CeO2 on the phase structure, compositions and other microstructures of 6063 aluminum surface laser cladding Ni-based cladding layer, to explore the effect and mechanism of rare earth oxide CeO2. The results showed that : Adding 5% CeO2 can effectively reduce the cracks and holes of Ni60 cladding layer, so that the cladding layer has a better structure morphology; The main phase structures of 5% CeO2 Ni60 cladding layer and Ni60 cladding layer both are β-NiAl (Cr) and a small amount of NiAl3, Ni3Al, Al, etc; After the addition of rare earth, the intensity of β-NiAl phase (110)、(200)、(211) diffraction peaks and Al peaks are significantly reduced, and there are clear peaks of NiAl3 phase; Compared with Ni60 cladding layer without adding rare earth CeO2, the Ni60 cladding layer added CeO2 have a uniform element distribution, a lower dilution rate; Adding 5% CeO2 can significantly reduce the porosity, refine the grain size and have more diffuse distribution grains at the surface of Ni60 cladding layer, but the effect is not obvious to the microstructure at the bottom of the cladding layer.

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引用本文

張光耀.稀土CeO2在6063Al表面Ni基激光熔覆中的作用機(jī)制[J].稀有金屬材料與工程,2016,45(4):1003~1007.[zhang guang yao. Mechanism of Rare Earth CeO2 on the Ni -Based Laser Cladding Layer of 6063 Al Surface[J]. Rare Metal Materials and Engineering,2016,45(4):1003~1007.]
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  • 收稿日期:2014-04-29
  • 最后修改日期:2014-09-29
  • 錄用日期:2014-10-30
  • 在線發(fā)布日期: 2016-06-02
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