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Co反點(diǎn)陣列薄膜的制備及形貌對(duì)其磁性的影響
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北京航空材料研究院創(chuàng)新基金項(xiàng)目(KF53090315)


Preparation of Co Antidot Arrays and the Effect of Morphology on Magnetic Properties
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    摘要:

    采用膠體晶體模板方法,通過變換聚苯乙烯(PS)微球粒徑和濺射時(shí)間制備了相同厚度的孔徑1~5 μm的Co反點(diǎn)陣列薄膜。利用掃描電子顯微鏡(SEM)、原子力顯微鏡(AFM)、X射線衍射(XRD)和振動(dòng)樣品磁強(qiáng)計(jì)(VSM)考察了樣品的結(jié)構(gòu)和磁學(xué)特性。發(fā)現(xiàn)Co反點(diǎn)陣列薄膜的矯頑力和剩磁比最大達(dá)到253.18×10-4 T和0.85,分別為Co薄膜的3.4和2.3倍,并且隨孔徑的增大逐漸降低。結(jié)合理論分析結(jié)果表明,Co反點(diǎn)陣列薄膜本身的形狀各向異性是其取得優(yōu)良磁學(xué)性能的原因,孔徑和孔間距這兩種形狀因素造成的形狀各向異性的變化是其磁性發(fā)生變化的物理本質(zhì)。

    Abstract:

    Highly ordered Co antidot arrays with different pore diameters (1.0,2.1,3.0,4.1, 5 μm) and the same thickness were prepared via sputtering Co into the gaps of PS colloidal crystal templates with different sputtering time. The structure and magnetic properties of Co antidot arrays were characterized by SEM, AFM, XRD and VSM. It is found that the coercivity and remanence ratio of Co antidot arrays are up to 253.18×10-4 T and 0.85, respectively, and they are 3.4 and 2.3 times larger than those of Co films, respectively. Moreover, with the increase of the pore diameter, the coercivity and the remanence ratio decrease gradually. The results of theoretical analysis indicate that the excellent magnetic characteristics come from the shape anisotropies induced by the structure itself, and the change of the shape anisotropies caused by pore diameter and pore spacing results in the change of the magnetic properties.

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祁洪飛,王錦鵬,劉大博. Co反點(diǎn)陣列薄膜的制備及形貌對(duì)其磁性的影響[J].稀有金屬材料與工程,2014,43(4):862~865.[Qi Hongfei, Wang Jinpeng, Liu Dabo. Preparation of Co Antidot Arrays and the Effect of Morphology on Magnetic Properties[J]. Rare Metal Materials and Engineering,2014,43(4):862~865.]
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  • 收稿日期:2013-04-05
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  • 在線發(fā)布日期: 2014-07-30
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