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Microstructure and Tensile Behavior of Ni-Base Metal Intermetallic Laminate Composites Prepared by Plasma Activated Sintering
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Microstructure and Tensile Behavior of Ni-Base Metal Intermetallic Laminate Composites Prepared by Plasma Activated Sintering
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National Natural Science Foundation of China (50571078); The Foundation of State Key Laboratory for Mechanical Behavior of Materials (20121203); Special Fund for Basic Scientific Research of Central Colleges, Chang’an University (CHD2011JC139)

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    摘要:

    采用等離子活化燒結(jié)法,通過Ni箔和Al箔的原位燃燒反應(yīng)制備了鎳基金屬/金屬間化合物疊層復(fù)合材料。微觀結(jié)構(gòu)觀察表明疊層由反應(yīng)層和剩余鎳層交替組成,且反應(yīng)層由多個金屬間化合物單層構(gòu)成。這些金屬間化合物相的成分呈梯度分布,且隨試樣處理溫度的升高,逐步由富鋁相向富鎳相轉(zhuǎn)變。相應(yīng)地,疊層復(fù)合材料的抗拉伸強度隨著溫度升高而逐漸升高,在1473 K溫度下制備的復(fù)合材料具有最高的抗拉伸強度和伸長率。拉伸試樣的斷口形貌顯示,在較低處理溫度(1073和1173 K)制備的疊層復(fù)合材料,其斷裂是由于金屬間化合物層內(nèi)的橫向裂紋與鎳層內(nèi)的剪切帶交互作用所引起的。隨著處理溫度升高,試樣的斷裂由多重裂紋模式向單裂紋模式轉(zhuǎn)變。

    Abstract:

    Ni-base metal-intermetallic laminate (MIL) composites were obtained from in-situ combustion reaction between the Ni and Al foils by a plasma activated sintering (PAS). Microstructural observation reveals that the laminates consist of alternate residual Ni layers and reacted layers which can be further divided into multiple layers of Ni-aluminides. The compositional gradient series of these intermetallic phases change in a stepwise fashion from Al-rich phases to Ni-rich phases with the increasing of the treatment temperature. Accordingly, the tensile strength of the composite increases steadily with the increase of temperature. The composites fabricated at 1473 K have the highest tensile strength and elongation. The fractographies of the tensile samples indicate that the failure of the composites treated at lower temperatures (1073 K and 1173 K) result from the interaction between the transversal cracks in the intermetallic layers and the shear bands in the Ni layers. When the treatment temperature increases, a transition from multiple cracking to a single cracking of the intermetallic layers can be observed.

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郭亞杰,史忠旗,徐義庫,喬冠軍,王 建. Microstructure and Tensile Behavior of Ni-Base Metal Intermetallic Laminate Composites Prepared by Plasma Activated Sintering[J].稀有金屬材料與工程,2014,43(4):813~818.[Guo Yajie, Shi Zhongqi, Xu Yiku, Qiao Guanjun, Wang Jian. Microstructure and Tensile Behavior of Ni-Base Metal Intermetallic Laminate Composites Prepared by Plasma Activated Sintering[J]. Rare Metal Materials and Engineering,2014,43(4):813~818.]
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  • 收稿日期:2013-04-17
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  • 在線發(fā)布日期: 2014-07-30
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