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Ag-IPMC物質(zhì)組分變化及失效機(jī)理研究
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哈爾濱工程大學(xué)

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國家“973”項(xiàng)目 (2011CB013403);國家自然科學(xué)基金 (51105377, 50971132);國家科技支撐項(xiàng)目 (2011BAF11B07)


Material Component Variation and Failure Mechanism Investigation of Ag-IPMC
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Harbin Engineering University

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    摘要:

    為了明確IPMC的失效機(jī)理,提高其使用壽命,以制備的Ag-IPMC為研究對象,對Ag-IPMC失效前、后的表面物質(zhì)組分變化進(jìn)行分析。采用能譜儀對選取的3處新制Ag-IPMC樣件表面和5處失效Ag-IPMC樣件表面進(jìn)行能譜掃描,分析Ag-IPMC樣件失效前、后其表面物質(zhì)組分的變化規(guī)律,研究Ag-IPMC表面物質(zhì)組分變化對運(yùn)動(dòng)失效的影響。結(jié)果表明:新制的Ag-IPMC樣件的表面Ag鍍層中幾乎沒有Ag的氧化物存在,并且Ag鍍層的導(dǎo)電性能優(yōu)良,為基膜內(nèi)離子的交換提供穩(wěn)定的電場環(huán)境;失效的Ag-IPMC樣件表面Ag元素含量降低,在電流作用下鍍層中的Ag與O和S發(fā)生反應(yīng),生成了氧化物和硫化物,使鍍層結(jié)構(gòu)產(chǎn)生類似于拉伸斷裂的現(xiàn)象,從而增大了Ag-IPMC表面鍍層的接觸電阻,導(dǎo)致Ag-IPMC失效。

    Abstract:

    In order to identify the failure mechanism of the IPMC and prolong service life, researching the prepared Ag-IPMC to analyze the changes of surface chemical components before and after the failure of IPMC. Three parts of active Ag-IPMC surfaces and five inactive Ag-IPMC surfaces selected were spectroscopy scanned by EDS to analyze the change rules of surface chemical components before and after the failure of IPMC and study the influence of changes of surface chemical components on movement failure. Results indicate that there was no oxide of Ag in the clad layer of active Ag-IPMC surfaces, and the Ag clad layer had a fine electrical conductivity, which provided an environment of steady electric field for the ion exchange in inophragma; the Ag content of inactive Ag-IPMC surfaces decreased, and Ag in clad layer reacted with O and S under the function of current, which generated the oxides and sulfides, making the structure of clad layer generate the phenomenon similar to fracture, and the increase of contact resistance of Ag-IPMC surfaces leaded to the failure of Ag-IPMC.

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徐巖. Ag-IPMC物質(zhì)組分變化及失效機(jī)理研究[J].稀有金屬材料與工程,2016,45(3):650~655.[xu yan. Material Component Variation and Failure Mechanism Investigation of Ag-IPMC[J]. Rare Metal Materials and Engineering,2016,45(3):650~655.]
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  • 收稿日期:2014-04-02
  • 最后修改日期:2014-05-04
  • 錄用日期:2014-05-15
  • 在線發(fā)布日期: 2016-07-07
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