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鋯材鎢極氬弧焊焊接件腐蝕機(jī)理
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Corrosion Mechanism of Zirconium Butt Joint by Tungsten Inert Gas Welding
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    摘要:

    采用X射線衍射、電化學(xué)測(cè)試,掃描電鏡觀察和能譜分析,系統(tǒng)研究了鎢極氬弧焊接鋯材焊縫區(qū)域的組織結(jié)構(gòu)及耐腐蝕性能,探究其腐蝕機(jī)理。結(jié)果表明:鋯材焊接件腐蝕方式為焊縫晶間腐蝕。產(chǎn)生晶間腐蝕的原因?yàn)椋簹鍤獗Wo(hù)不充分及焊絲含有少量的氧,在焊縫區(qū)域晶界形成了鋯的氧化物,導(dǎo)致晶界與晶粒內(nèi)部存在電化學(xué)不均勻性,致使晶界的溶解電流密度大于晶粒,發(fā)生晶間腐蝕

    Abstract:

    In order to solve the corrosion issues that occur in the weld zone (WZ) of zirconium material applied in the industrial community, X-ray diffraction (XRD), electrochemical analysis, scanning electron microscope (SEM) and energy dispersive spectrometer (EDS) were used to investigate the microstructure and corrosion resistance of the zirconium butt joint by tungsten inert gas (TIG) welding. Also, the mechanism of corrosion was discussed. It is found that the corrosion pattern of zirconium butt joint is intergranular corrosion. The factors that cause intergranular corrosion are the inadequate protection of argon and a trace amount of oxygen existing in the soldering wires, which facilitates the generation of zirconium composite oxides that result in the electrochemical inhomogeneity between crystal boundaries and particles. Consequently, the dissolve current density of crystal boundaries is larger than that of the grains, which leads to intergranular corrosion

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羅西希,姚正軍,魏東博,李 婷,朱俊謀,周文斌.鋯材鎢極氬弧焊焊接件腐蝕機(jī)理[J].稀有金屬材料與工程,2014,43(3):676~681.[Luo Xixi, Yao Zhengjun, Wei Dongbo, Li Ting, Zhu Junmou, Zhou Wenbin. Corrosion Mechanism of Zirconium Butt Joint by Tungsten Inert Gas Welding[J]. Rare Metal Materials and Engineering,2014,43(3):676~681.]
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  • 收稿日期:2013-03-20
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  • 在線發(fā)布日期: 2014-06-27
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