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急冷Ag-Cu-Ge釬料薄帶性能與釬焊界面特征
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昆明貴金屬研究所

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國(guó)家自然科學(xué)基金項(xiàng)目(面上項(xiàng)目,重點(diǎn)項(xiàng)目,重大項(xiàng)目)


Properties and Brazing Interface Characteristicsof Rapidly Solidified Ag-Cu-Ge Solder Ribbon
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Kunming Institute of Precious Metals

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    摘要:

    采用急法制備了Ag-Cu-Ge共晶釬料薄帶。用DSC、XRD分析釬料合金的熔化溫度及相組成。用掃描電子顯微鏡(SEM)觀察釬料合金以及釬焊接頭的組織形貌,并用能譜儀(EDS)進(jìn)行成分分析。結(jié)果表明:急冷Ag-Cu-Ge釬料液相線降低了4.8℃,熔化區(qū)間減小了4.4℃;鑄態(tài)釬料組織粗大,偏析嚴(yán)重,急冷態(tài)釬料組織顯著細(xì)化,成分更加均勻;與同成分的普通釬料相比,急冷Ag-Cu-Ge釬料與銅和鎳基體的潤(rùn)濕性和鋪展性更好,過(guò)渡層的厚度更寬,釬焊接頭剪切強(qiáng)度更高;釬料合金與銅母材形成層狀固液同分化合物,而與鎳母材形成了筍狀固液異分化合物,這種嵌入式結(jié)構(gòu)有利于提高釬焊接頭的牢固性。

    Abstract:

    Ag-Cu-Ge eutectic solder ribbons were prepared by single roller rapid solidification. Melting temperature and phase composition of solder alloys were determined by DSC and XRD. The microstructure and morphology of solder alloys and brazing joints were observed by scanning electron microscope (SEM), and the chemical composition was analyzed by energy dispersive spectrometer (EDS). The results show that the liquidus temperature of rapidly solidified Ag-Cu-Ge solder decreases 4.8℃ and its melting temperature range reduces 4.4℃. The microstructure of cast solder is massive and heavy segregation, while rapidly solidified solder has finer microstructures and higher composition homogeneity; Rapidly solidified Ag-Cu-Ge solder has a better wettability and spreadability, wider transition layer thickness and higher shear strength of brazed joints with Cu and Ni substrate compared with the same constituent common solder. Congruent compounds which grows up as a layer is found on the interface of solder alloy with copper substrate, while incongruent compounds which grows up as bamboo shoot form is found on the interfaces of solder alloy and substrate. This embedded structure is helpful to improve the strength of brazed joints

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張利廣.急冷Ag-Cu-Ge釬料薄帶性能與釬焊界面特征[J].稀有金屬材料與工程,2016,45(2):421~425.[zhangliguang. Properties and Brazing Interface Characteristicsof Rapidly Solidified Ag-Cu-Ge Solder Ribbon[J]. Rare Metal Materials and Engineering,2016,45(2):421~425.]
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  • 收稿日期:2014-03-14
  • 最后修改日期:2014-04-03
  • 錄用日期:2014-04-15
  • 在線發(fā)布日期: 2016-07-19
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