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鎂-鎳/石墨烯復(fù)合物的儲(chǔ)氫性能
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國(guó)家自然科學(xué)基金(51071085, 51171079);江蘇高校優(yōu)勢(shì)學(xué)科建設(shè)工程資助項(xiàng)目


Hydrogen Storage Properties of Mg-Ni/Graphene Composites
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    摘要:

    分別通過物理法和化學(xué)法制備石墨烯載鎳催化劑 (Ni/Graphene),并采用球磨預(yù)處理或超聲分散的方式與鎂粉混勻,結(jié)合氫化燃燒合成和機(jī)械球磨復(fù)合技術(shù)制備鎂-鎳/石墨烯(Mg-Ni/Graphene)復(fù)合物儲(chǔ)氫材料。采用X射線衍射儀、掃描電鏡及氣體反應(yīng)控制器研究了材料的相組成、微觀形貌和吸放氫性能。比較發(fā)現(xiàn),添加化學(xué)法制備的Ni/Graphene并采用球磨預(yù)處理的Mg-Ni/Graphene復(fù)合物具有最佳的吸放氫性能,復(fù)合物的起始放氫溫度降低,放氫速率加快。其在373 K溫度下,100 s內(nèi)就基本能達(dá)到飽和吸氫量6.21%(質(zhì)量分?jǐn)?shù));553 K,1800 s內(nèi)完全放氫,且放氫量達(dá)到6.05%。球磨預(yù)處理使得Ni/Graphene更均勻的與Mg接觸,利于發(fā)揮Ni的催化作用和石墨烯優(yōu)異的導(dǎo)電導(dǎo)熱性?;瘜W(xué)法制備的Ni/Graphene原位還原出納米晶Ni,有利于形成納米級(jí)Mg2NiH4晶粒,促進(jìn)復(fù)合物儲(chǔ)氫性能的改善。

    Abstract:

    Graphene supported nickel catalysts (Ni/Graphene) were synthesized by physical method and chemical method, respectively. The as prepared Ni/Graphene was further mixed with Mg by ball milling pretreatment or ultrasonic dispersion. Then the well mixed powders were used to prepare Mg-Ni/Graphene composites by the combined process of hydriding combustion synthesis and mechanical milling (HCS+MM). The phase compositions, surface morphologies and hydriding/dehydriding properties of the samples were examined by X-ray diffraction (XRD), scanning electron microscopy (SEM) and gas reaction controller (GRC). Results show that the Mg-Ni/Graphene composite which mixed Ni/Graphene synthesized by chemical method and Mg through ball milling pretreatment exhibits the best hydriding/dehydriding properties. It has the lowest onset hydrogen desorption temperature and faster dehydrogenation rate. About 6.21 % hydrogen can be absorbed within 100 s at 373 K, and 6.05 % hydrogen can be desorbed within 1800 s at 553 K. Ball milling pretreatment makes Ni/Grapheme and Mg contact homogeneous, thus the excellent thermal?and?electrical conductivity of Grapheme and the catalytic effect of Ni are enhanced. In addition, nano-crystalline Ni with smaller grain size synthesized by chemical method is helpful to the formation of nanosized Mg2NiH4 grains, leading to the improvement in hydrogen storage properties of the composite.

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宦清清,朱云峰,衛(wèi)靈君,李李泉.鎂-鎳/石墨烯復(fù)合物的儲(chǔ)氫性能[J].稀有金屬材料與工程,2014,43(2):356~360.[Huan Qingqing, Zhu Yunfeng, Wei Lingjun, Li Liquan. Hydrogen Storage Properties of Mg-Ni/Graphene Composites[J]. Rare Metal Materials and Engineering,2014,43(2):356~360.]
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  • 收稿日期:2013-01-15
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  • 在線發(fā)布日期: 2014-06-03
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