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Cu-Zr-Ag-Al非晶合金晶化過程的動(dòng)力學(xué)效應(yīng)
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蘭州理工大學(xué)

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TG249.9

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國(guó)家自然科學(xué)基金資助(項(xiàng)目號(hào)51061008)


Kinetic Effect in the Crystallization Process of Cu-Zr-Ag-Al Bulk Metallic Glass
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Lanzhou University of Technology

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    摘要:

    采用銅模吸鑄法制備了直徑3 mm的Cu40Zr44Ag8Al8大塊非晶合金(BMGs),并分別采用X射線衍射儀(XRD)和同步示差掃描量熱儀(DSC)對(duì)其晶化過程中顯微結(jié)構(gòu)的演變及其晶化動(dòng)力學(xué)進(jìn)行研究。結(jié)果顯示:該BMGs在晶化過程中依次從非晶基體中析出Al3Zr和Cu10Zr7相。采用Kissinger和Ozawa方法計(jì)算的非晶樣品第一晶化峰的晶化激活能分別為315.69 kJ/mol和312.65 kJ/mol,該非晶合金具有很強(qiáng)的熱穩(wěn)定性。此外,該非晶合金晶化過程具有很強(qiáng)的動(dòng)力學(xué)效應(yīng),特征溫度對(duì)升溫速率的依賴性遵循Lasocka方程,但其晶化機(jī)理函數(shù)卻無明顯的動(dòng)力學(xué)效應(yīng),與加熱速率無關(guān)。采用GM模型對(duì)30 K/min加熱速率下的DSC實(shí)驗(yàn)數(shù)據(jù)進(jìn)行擬合,發(fā)現(xiàn)其擬合參數(shù)由λi=5.2,n=3.4變?yōu)棣薸=2.5,n=4,說明該非晶合金的晶化行為遵循形核率隨時(shí)間不斷增加的初晶型晶化規(guī)律。

    Abstract:

    Copper-mold suction casting was employed for the Cu40Zr44Ti8Al8 bulk metallic glasses (BMGs) preparation. X-ray diffraction (XRD) and differential scanning calorimetry (DSC) were used to analyze the microstructure evlution and crystallization kinetics of the samples. Results show that Al3Zr and Cu10Zr7 precipetate from the amorphous matrix successively. The activation enevey of the first crystallization peak calcultaiton by the Kissinger and Ozawa method are 315.69 kJ/mol and 312.65 kJ/mol, so the BMGs are highly thermal stable. Crystallization process of the BMGs shows obvious kinetic effect. The dependence of the characteristic temperatures on the heating rate follows Lasocka equation. But crystallization mechanism of the BMGs hardly shows any kinetic effect and has nothing to do with heating rate. Parameters fitted by the GM medol under the heating rate of 30 K/min change form λi=5.2,n=3.4 to λi=2.5,n=4, indicating that the BMGs experienced an increasing nucleation and growth rates in the primary crystallization process.

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張香云,袁子洲,馮雪磊,崔立治,李斷弦. Cu-Zr-Ag-Al非晶合金晶化過程的動(dòng)力學(xué)效應(yīng)[J].稀有金屬材料與工程,2016,45(1):141~144.[ZhangXiangyun, Yuan Zizhou, Feng Xuelei, Cui Lizhi, Li Duanxian. Kinetic Effect in the Crystallization Process of Cu-Zr-Ag-Al Bulk Metallic Glass[J]. Rare Metal Materials and Engineering,2016,45(1):141~144.]
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  • 收稿日期:2014-02-20
  • 最后修改日期:2014-03-18
  • 錄用日期:2014-04-08
  • 在線發(fā)布日期: 2019-01-04
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